Lanthanum (La)
lanthanideSolid
Masse atomique relative standard
138,90547 uConfiguration électronique
[Xe] 6s2 5d1Point de fusion
917,85 °CPoint d’ébullition
3463,85 °CMasse volumique
6150 kg/m³États d’oxydation
0, +1, +2, +3Électronégativité (Pauling)
1,1Énergie d’ionisation (1re)
5,5769 eVAnnée de découverte
1839Rayon atomique
195 pmDétails
Lanthanum is the first element of the lanthanide series by common convention, although its 4f shell is empty in the neutral atom. It is a soft, reactive rare-earth metal that occurs with other light rare earths in minerals such as monazite and bastnäsite. Its chemistry is dominated by the large La³⁺ ion, which gives mostly colorless, strongly ionic compounds. Lanthanum is important in optical glass, catalysts, battery alloys, and high-temperature ceramic materials.
Lanthanum is silvery white, malleable, ductile, and soft enough to be cut with a knife. It is one of the most reactive of the rare-earth metals. It oxidizes rapidly when exposed to air. Cold water attacks lanthanum slowly, while hot water attacks it much more rapidly.
The metal reacts directly with elemental carbon, nitrogen, boron, selenium, silicon, phosphorus, sulfur, and with halogens.
At 310°C, lanthanum changes from a hexagonal to a face-centered cubic structure, and at 865°C it again transforms into a body-centered cubic structure.
The name derives from the Greek lanthanein for "to be hidden" or "to escape notice" because it hid in cerium ore and was difficult to separate from that rare earth mineral. Lanthanum was discovered by the Swedish surgeon and chemist Carl-Gustav Mosander in 1839. In 1842, Mosander separated his lanthanium sample into two oxides; for one of these he retained the name lanthanum and for the other he gave the name didymium (or twin).
Lanthanum was discovered by Carl Gustaf Mosander, a Swedish chemist, in 1839. Mosander was searching for impurities he believed existed within samples of cerium. He treated cerium nitrate (Ce(NO3)3) with dilute nitric acid (HNO3) and found a new substance he named lanthana (La2O3). Roughly 0.0018% of the earth's crust is composed of lanthanum. Today, lanthanum is primarily obtained through an ion exchange process from monazite sand ((Ce, La, Th, Nd, Y)PO4), a material rich in rare earth elements that can contain as much as 25% lanthanum.
From the Greek word lanthanein, to escape notice. Mosander in 1839 extracted lanthana from impure cerium nitrate and recognized the new element.
Lanthanum was isolated in relatively pure form in 1923. Iron exchange and solvent extraction techniques have led to much easier isolation of the so-called "rare-earth" elements.
Pure lanthanum is a silvery-white, soft metal that can be cut with a knife when freshly prepared. It tarnishes rapidly in air, forming oxide and hydroxide films, and reacts slowly with cold water but more rapidly when finely divided or heated.
Lanthanum is used in high-refractive-index optical glasses for camera lenses, microscopes, and other precision optics. Mixed rare-earth metal rich in lanthanum has been used in lighter flints and spark-producing alloys. Lanthanum-containing nickel-metal hydride battery alloys store hydrogen reversibly. Lanthanum compounds are also used in fluid catalytic cracking catalysts, ceramic capacitors and dielectric materials, phosphors, and as additives in tungsten electrodes and specialty steels.
Lanthanum is one of the rare earth elements used to make carbon arc lights which are used in the motion picture industry for studio lighting and projector lights. Lanthanum also makes up about 25% of Misch metal, a material that is used to make flints for lighters. Lanthana (La2O3) is used to make the glass used in camera lenses and in other special glasses.
Rare-earth compounds containing lanthanum are extensively used in carbon lighting applications, especially by the motion picture industry for studio lighting and projection. This application consumes about 25 percent of the rare-earth compounds produced. La2O3 improves the alkali resistance of glass, and is used in making special optical glasses. Small amounts of lanthanum, as an additive, can be used to produce nodular cast iron.
There is current interest in hydrogen sponge alloys containing lanthanum. These alloys take up to 400 times their own volume of hydrogen gas, and the process is reversible. Every time they take up the gas, heat energy is released; therefore these alloys have possibilities in an energy conservation system.
Isotopes in Earth/Planetary Science
Studies have shown that 138La (with a half-life of 1.06×1011 years) can be used along with 138Ce and 136Ce to measure time elapsed from a supernova explosion producing large numbers of neutrinos [415] T. Hayakawa, T. Shizuma, T. Kajino, K. Ogawa, H. Nakada. Am. Phys. Soc.77, (2008)..
Isotopes in Geochronology
138La decays to 138Ce and 138Ba, respectively, by beta decay with a half-life of 1.06×1011 years and by electron capture with a half-life of 1.56×1011 years. The isotope-amount ratio n(138Ce)/n(142Ce) has been used for dating rocks on long time scales (billions of years) and as a chemical tracer in geochemistry [416] T. Hayashi, M. Tanimizu, T. Tanaka. Precambrian Res.135, 345 (2004).. The increase in radiogenic 138Ba in rocks enriched in rare earth elements, such as allanite, enables one to determine the age of such rocks (Fig. IUPAC.57.1) [417] S. Nakai, H. Shimizu, A. Masuda. Nature320, 433 (1986)..
Isotopes Used as a Source of Radioactive Isotope(s)
139La is used for the production of the medical radioisotope 139Ce via the 139La (p, n) 139Ce reaction [418] H. Aglan, S. A. Kandil, H. A. Hanafi, M. A. Mousa, Z. A. Saleh. J. Radioanal. Nucl. Chem.280, 533 (2009)..
Lanthanum almost exclusively forms compounds in the +3 oxidation state. Lanthanum oxide (La₂O₃) is a basic oxide used in optical glass and ceramics and readily absorbs moisture and CO₂ from air. Lanthanum chloride (LaCl₃), lanthanum nitrate (La(NO₃)₃), and lanthanum carbonate (La₂(CO₃)₃) are common salts of the La³⁺ ion. Lanthanum hexaboride (LaB₆) is a refractory conductor valued as an electron-emission material. Lanthanum strontium manganite, often written La₁₋ₓSrₓMnO₃, is important in oxide electronics and solid oxide fuel-cell cathodes.
See more information at the Lanthanum compound page.
Metallic lanthanum dust and turnings are flammable, and the metal reacts with moisture to release hydrogen. Soluble lanthanum salts can irritate skin, eyes, and the respiratory tract and may disturb calcium-related biological processes at sufficient exposure. Lanthanum has no established essential biological role. Natural lanthanum is effectively stable; radiological risk normally comes from associated thorium or uranium in ores, not from lanthanum itself.
Lanthanum and its compounds have a low to moderate acute toxicity rating; therefore, care should be taken in handling them.
Lanthanum occurs dispersed in the crust with other rare-earth elements and is concentrated mainly in phosphate and carbonate minerals. Weathering releases La³⁺ into soils and waters, where it tends to bind strongly to clays, organic matter, phosphates, and carbonates rather than remain highly mobile. Mining and processing can increase local rare-earth, acid, fluoride, and radionuclide burdens, depending on ore type and waste management.
Lanthanum is obtained chiefly as a co-product of rare-earth mining and separation, especially from bastnäsite and monazite concentrates. Separation relies on solvent extraction or ion-exchange processes because neighboring rare earths have very similar chemistry. It is one of the more abundant and lower-cost rare earths, but supply depends on integrated rare-earth processing capacity and demand for other elements in the same ores. Recycling occurs in limited streams such as nickel-metal hydride batteries and some catalysts, while optical glass and ceramics are less commonly recovered for lanthanum content.
Lanthanum is found in rare-earth minerals such as cerite, monazite, allanite, and bastnasite. Monazite and bastnasite are principal ores in which lanthanum occurs in percentages up to 25 percent and 38 percent respectively. Misch metal, used in making lighter flints, contains about 25 percent lanthanum.
The availability of lanthanum and other rare earths has improved greatly in recent years. The metal can be produced by reducing the anhydrous fluoride with calcium.
Lanthanum is an odd-atomic-number heavy element made mainly by neutron-capture processes followed by radioactive decay in earlier generations of stars. It is far less abundant cosmically than iron-group elements but is measurable in the Sun, meteorites, and many old stars. Its abundance pattern helps distinguish slow and rapid neutron-capture contributions in stellar material.
- Lanthanum metal expands when it solidifies, an uncommon behavior among metals.
- The name comes from Greek lanthanein, meaning to lie hidden, because it was found concealed in cerium minerals.
- La³⁺ is diamagnetic because it has no 4f electrons.
- Lanthanum hexaboride cathodes can emit electrons efficiently at high temperature.
- Lanthanum carbonate is used as a phosphate binder in some medical applications.
Images
Propriétés
Propriétés physiques
- Rayon atomique (empirique)
- 195 pm Comparer : Rayon atomique (empirique) de tous les éléments →
- Rayon covalent
- 207 pm Comparer : Rayon covalent de tous les éléments →
- Rayon de van der Waals
- 240 pm Comparer : Rayon de van der Waals de tous les éléments →
- Rayon métallique
- 169 pm Comparer : Rayon métallique de tous les éléments →
- Masse volumique
- 6150 kg/m³ Comparer : Masse volumique de tous les éléments →
- Volume molaire
- 0,0225 L/mol
- Phase aux CNTP
- Solide Comparer : Phase aux CNTP de tous les éléments →
- Point de fusion
- 917,85 °C Comparer : Point de fusion de tous les éléments →
- Point d’ébullition
- 3463,85 °C Comparer : Point d’ébullition de tous les éléments →
- Conductivité thermique
- 13,4 W/(m·K) Comparer : Conductivité thermique de tous les éléments →
- Capacité thermique massique
- 0,195 J/(g·K) Comparer : Capacité thermique massique de tous les éléments →
- Capacité thermique molaire
- 27,11 J/(mol·K) Comparer : Capacité thermique molaire de tous les éléments →
- Structure cristalline
- Hexagonal compact Comparer : Structure cristalline de tous les éléments →
Propriétés chimiques
- Électronégativité (Pauling)
- 1,1 Comparer : Électronégativité (Pauling) de tous les éléments →
- Affinité électronique
- 0,47 eV
- Énergie d’ionisation (1re)
- 5,5769 eV Comparer : Énergie d’ionisation (1re) de tous les éléments →
- Énergie d’ionisation (2e)
- 11,184999 eV Comparer : Énergie d’ionisation (2e) de tous les éléments →
- Énergie d’ionisation (3e)
- 19,177366 eV Comparer : Énergie d’ionisation (3e) de tous les éléments →
- Énergie d’ionisation (4e)
- 49,950172 eV Comparer : Énergie d’ionisation (4e) de tous les éléments →
- Énergie d’ionisation (5e)
- 61,600212 eV Comparer : Énergie d’ionisation (5e) de tous les éléments →
- États d’oxydation
- 0, +1, +2, +3 Comparer : États d’oxydation de tous les éléments →
- Électrons de valence
- 3 Comparer : Électrons de valence de tous les éléments →
- Configuration électronique
- [Xe] 6s2 5d1
Propriétés thermodynamiques
- Enthalpie de fusion
- 0,06425869 eV Comparer : Enthalpie de fusion de tous les éléments →
- Enthalpie de vaporisation
- 4,145722 eV Comparer : Enthalpie de vaporisation de tous les éléments →
- Enthalpie de sublimation
- 4,467016 eV
- Enthalpie d’atomisation
- 4,467016 eV
- Enthalpie d’atomisation
- 4,467016 eV
Propriétés nucléaires
- Protons
- 57 Comparer : Protons de tous les éléments →
- Neutrons
- 82 Comparer : Neutrons de tous les éléments →
- Isotopes connus
- 42 Comparer : Isotopes connus de tous les éléments →
- Isotopes stables
- 1 Comparer : Isotopes stables de tous les éléments →
- Isotope le plus stable
- La-139
- Année de découverte
- 1839
Abondance
- Abondance (croûte terrestre)
- 39 mg/kg Comparer : Abondance (croûte terrestre) de tous les éléments →
- Abondance (océan)
- 3,4 × 10−6 mg/L Comparer : Abondance (océan) de tous les éléments →
Structure cristalline
- Paramètre de maille a
- 375 pm
Structure électronique
- Électrons par couche
- 2, 8, 18, 18, 9, 2 Comparer : Électrons par couche de tous les éléments →
Identifiants
- Numéro CAS
- 7439-91-0 Comparer : Numéro CAS de tous les éléments →
- Symbole de terme
- 2D3/2
- InChI
- InChI=1S/La
- Clé InChI
- FZLIPJUXYLNCLC-UHFFFAOYSA-N
Configuration électronique Mesuré
La: 5d¹ 6s²[Xe] 5d¹ 6s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 5d¹ 6s²Modèle atomique
Les isotopes diffèrent par leur nombre de neutrons, leur masse et leur stabilité — pas par la configuration électronique de l’atome neutre.
Modèle atomique schématique, non à l’échelle.
Empreinte atomique
Spectre d’émission / d’absorption
Distribution isotopique
| Nombre de masse | Masse atomique (u) | Abondance naturelle | Demi-vie |
|---|---|---|---|
| 139 Stable | 138,9063563 ± 0,0000024 | 99,9112% | Stable |
Phase / État
Explication: 892,9 °C en dessous du point de fusion (917,85 °C)
Schématique, non à l’échelle
Points de transition de phase
Énergies de transition
Énergie nécessaire pour faire fondre 1 mol au point de fusion
Énergie nécessaire pour vaporiser 1 mol au point d’ébullition
Énergie nécessaire pour sublimer 1 mol au point de sublimation
Masse volumique
Dans les conditions standard
Dans les conditions standard
Spectres atomiques
Affichage de 10 sur 57. Tri par charge ionique croissante.
Raies répertoriées ?
| Ion | Charge | Nombre total de raies | Probabilités de transition | Désignations des niveaux |
|---|---|---|---|---|
| La I | 0 | 393 | 315 | 393 |
| La II | +1 | 273 | 84 | 273 |
| La III | +2 | 122 | 0 | 0 |
| La IV | +3 | 87 | 0 | 0 |
| La V | +4 | 42 | 0 | 0 |
Niveaux répertoriés ?
| Ion | Charge | Niveaux |
|---|---|---|
| La I | 0 | 343 |
| La II | +1 | 119 |
| La III | +2 | 42 |
| La IV | +3 | 52 |
| La V | +4 | 37 |
| La VI | +5 | 2 |
| La VII | +6 | 2 |
| La VIII | +7 | 2 |
| La IX | +8 | 2 |
| La X | +9 | 2 |
Rayons ioniques
| Charge | Coordinence | Spin | Rayon |
|---|---|---|---|
| +3 | 6 | N/D | 103.2 pm |
| +3 | 7 | N/D | 110.00000000000001 pm |
| +3 | 8 | N/D | 115.99999999999999 pm |
| +3 | 9 | N/D | 121.6 pm |
| +3 | 10 | N/D | 127 pm |
| +3 | 12 | N/D | 136 pm |
Composés
Isotopes (1)
Natural lanthanum is a mixture of two stable isotopes, 138La and 139La. Twenty three other radioactive isotopes are recognized.
| Nombre de masse | Masse atomique (u) | Abondance naturelle | Demi-vie | Mode de désintégration | |
|---|---|---|---|---|---|
| 139 Stable | 138,9063563 ± 0,0000024 | 99,9112% ± 0,0007% | Stable | stable |
Propriétés étendues
Rayons covalents (données étendues)
- Rayon covalent (Pyykkö)
- 180 pm
- Rayon covalent (Pyykkö, liaison double)
- 139 pm
- Rayon covalent (Pyykkö, liaison triple)
- 139 pm
Rayons de van der Waals
- Batsanov
- 250 pm
- Alvarez
- 298 pm
- UFF
- 352,2 pm
- MM3
- 278 pm
Rayons atomiques et métalliques
- Rayon atomique (Rahm)
- 284 pm
- Rayon métallique (C12)
- 187 pm
Échelles de numérotation
- Mendeleev
- 13
- Pettifor
- 33
- Glawe
- 32
Échelles d’électronégativité
- Ghosh
- 0
- Miedema
- 3
- Gunnarsson–Lundqvist
- 4
- Robles–Bartolotti
- 3
Polarisabilité et dispersion
- Polarisabilité dipolaire
- 215 a.u.
- Polarisabilité dipolaire (incertitude)
- 20 a.u.
- C₆ (Gould–Bučko)
- 3730 Ha·Bohr6
Affinité chimique
- Affinité protonique
- 1013 kJ/mol
- Basicité en phase gazeuse
- 991,9 kJ/mol
Paramètres de Miedema
- Volume molaire de Miedema
- 22,55 cm3/mol
- Densité électronique de Miedema
- 2
Risque d’approvisionnement et économie
- Concentration de la production
- 97
- Risque relatif d’approvisionnement
- 10
- Répartition des réserves
- 50
- Stabilité politique (principal producteur)
- 24
- Stabilité politique (principal détenteur de réserves)
- 24
Transitions de phase et allotropes
| Point de fusion | 1193,15 K |
| Point d’ébullition | 3737,15 K |
Catégories d’états d’oxydation
Données de référence avancées
Constantes d’écran (13)
| n | Orbitale | σ |
|---|---|---|
| 1 | s | 1,1317 |
| 2 | p | 4,2044 |
| 2 | s | 15,0466 |
| 3 | d | 13,9398 |
| 3 | p | 18,8604 |
| 3 | s | 19,0569 |
| 4 | d | 32,2748 |
| 4 | f | 55,64 |
| 4 | p | 29,2936 |
| 4 | s | 28,2036 |
Détail des rayons cristallins (6)
| Charge | CN | Spin | rcrystal (pm) | Origine |
|---|---|---|---|---|
| 3 | VI | 117,2 | from r^3 vs V plots, | |
| 3 | VII | 124 | ||
| 3 | VIII | 130 | from r^3 vs V plots, | |
| 3 | IX | 135,6 | from r^3 vs V plots, | |
| 3 | X | 141 | ||
| 3 | XII | 150 | calculated, |
Modes de désintégration des isotopes (64)
| Isotope | Mode | Intensité |
|---|---|---|
| 116 | B+ | — |
| 116 | B+p | — |
| 116 | p | — |
| 117 | p | 100% |
| 117 | B+ | — |
| 117 | B+p | — |
| 118 | B+ | — |
| 118 | B+p | — |
| 119 | B+ | — |
| 120 | B+ | 100% |
Facteurs de diffusion des rayons X (711)
| Énergie (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 3,31251 |
| 10,1152 | — | 3,28769 |
| 10,2317 | — | 3,26306 |
| 10,3496 | — | 3,23861 |
| 10,4688 | — | 3,20975 |
| 10,5894 | — | 3,15961 |
| 10,7114 | — | 3,11024 |
| 10,8348 | — | 3,06165 |
| 10,9596 | — | 3,01382 |
| 11,0859 | — | 2,96673 |
Données complémentaires
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
3.9×101 milligrams per kilogram
Références (1)
- [5] Lanthanum https://education.jlab.org/itselemental/ele057.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
3.4×10-6 milligrams per liter
Références (1)
- [5] Lanthanum https://education.jlab.org/itselemental/ele057.html
Sources
Sources of this element.
Lanthanum is found in rare-earth minerals such as cerite, monazite, allanite, and bastnasite. Monazite and bastnasite are principal ores in which lanthanum occurs in percentages up to 25 percent and 38 percent respectively. Misch metal, used in making lighter flints, contains about 25 percent lanthanum.
The availability of lanthanum and other rare earths has improved greatly in recent years. The metal can be produced by reducing the anhydrous fluoride with calcium.
Références (1)
- [6] Lanthanum https://periodic.lanl.gov/57.shtml
Références
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
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The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Lanthanum.
The element property data was retrieved from publications.