Germanium (Ge)
metalloidSolid
Masse atomique relative standard
72,63 uConfiguration électronique
[Ar] 4s2 3d10 4p2Point de fusion
938,25 °CPoint d’ébullition
2832,85 °CMasse volumique
5323,4 kg/m³États d’oxydation
−4, −3, −2, −1, 0, +1, +2, +3, +4Électronégativité (Pauling)
2,01Énergie d’ionisation (1re)
7,899435 eVAnnée de découverte
1886Rayon atomique
125 pmDétails
Germanium is a hard, brittle metalloid in group 14, chemically intermediate between silicon and tin. It is a covalent semiconductor with a narrow band gap and forms stable compounds mainly in the +4 and +2 oxidation states. The element is not mined as a principal ore in most operations; it is commonly recovered as a by-product from zinc processing and from some coal-derived materials. Its technological importance rests on infrared optics, fiber-optic materials, semiconductor devices, and specialty catalysts.
The element is a gray-white metalloid. In pure state, the element is crystalline and brittle, retaining its luster in air at room temperature. It is a very important semiconductor. Zone-refining techniques have led to production of crystalline germanium for semiconductor use with an impurity of only one part in 1010.
The name derives from the Latin germania for Germany. It was discovered and isolated by the German chemist Clemens-Alexander Winkler in 1886 in the mineral argyrodite (GeS2×4Ag2S).
First proposed to exist by Dmitri Mendeleyev in 1871 based on gaps in his newly created Periodic Table of Elements, germanium was discovered by the German chemist Clemens Winkler in the mineral argyrodite (Ag8GeS6) in 1886. Today, germanium is primarily obtained from the smelting of zinc ores and from the byproducts of burning certain types of coal.
From the Latin word Germania, Germany. Mendeleev predicted the existence of Germanium in 1871 as ekasilicon, and the element was discovered by Winkler in 1886.
Pure germanium is a lustrous, grayish-white solid with a metallic sheen. It crystallizes in the diamond-cubic structure and is brittle rather than malleable. High-purity material is commonly encountered as polycrystalline pieces, single-crystal ingots, or wafers for electronic and optical use.
Germanium is used where its optical and electronic properties are valuable rather than as a structural metal. Germanium dioxide, GeO₂, is added to silica glass for optical fibers because it raises refractive index. Elemental germanium and germanium-containing glasses are used in infrared lenses, windows, and thermal imaging optics. Germanium substrates support some high-efficiency multijunction solar cells. Small amounts are used in semiconductor detectors, legacy transistors, and SiGe alloys for high-speed electronics. Certain organogermanium and oxide materials have specialized roles, but broad medical uses are not established.
The largest use of germanium is in the semiconductor industry. When doped with small amounts of arsenic, gallium, indium, antimony or phosphorus, germanium is used to make transistors for use in electronic devices. Germanium is also used to create alloys and as a phosphor in fluorescent lamps. Both germanium and germanium oxide (GeO) are transparent to infrared radiation and are used in infrared optical instruments and infrared detectors. Some germanium compounds seem to be effective in killing some types of bacteria and are currently being studied for use in chemotherapy.
When germanium is doped with arsenic, gallium, or other elements, it is used as a transistor element in thousands of electronic applications. The most common use of germanium is as a semiconductor. Germanium is also finding many other applications including use as an alloying agent, as a phosphor in fluorescent lamps, and as a catalyst.
Germanium and germanium oxide are transparent to the infrared and are used in infrared spectroscopes and other optical equipment, including extremely sensitive infrared detectors.
The high index of refraction and dispersion properties of its oxide's have made germanium useful as a component of wide-angle camera lenses and microscope objectives.
The field of organo-germanium chemistry is becoming increasingly important. Certain germanium compounds have a low mammalian toxicity, but a marked activity against certain bacteria, which makes them useful as chemotherapeutic agents.
Isotopes in Earth/Planetary Science
Because molecules, atoms, and ions of the stable isotopes of germanium possess slightly different physical and chemical properties, they commonly will be fractionated during physical, chemical, and biological processes, giving rise to variations in isotopic abundances and in atomic weights. There are measureable variations in the isotopic abundances of germanium in terrestrial materials (Fig. IUPAC.32.1).
Isotopes in Medicine
68Ge is used to calibrate positron emission tomography (PET) scanners, which have been used for medical diagnostic procedures [268] Office of Science, Los Alamos National Laboratory. Isotope Production and Applications, Los Alamos National Laboratory (2017), Feb. 26; http://www.lanl.gov/science-innovation/science-programs/office-of-science-programs/nuclear-physics/isotopes/_assets/docs/isotope-program-brochure.pdf..
Isotopes Used as a Source of Radioactive Isotope(s)
72Ge and 74Ge are used to produce the radioactive isotopes 72As and 74As, with half-lives of 26 h and 17.8 days, respectively. The arsenic nuclei can attach to tumors and the decay of these isotopes is used to image the location of cancerous tumors in vivovia the 72Ge (n, p) 72As reaction and the 74Ge (n, p) 74As reaction [269] M. Jennewein, M. A. Lewis, D. Zhao, E. Tsyganov, N. Slavine, J. He, L. Watkins, V. D. Kodibagkar, S. O’Kelly, P. Kulkarni, P. P. Antich, A. Hermanne, F. Rösch, R. P. Mason, P. E. Thorpe. Clin. Cancer Res.14, 1377 (2008).. 70Ge, 72Ge, and 74Ge have all been used to produce the medical radioisotope 73Se via the 70Ge (4He, n) 73Se reaction, via the 72Ge (4He, 3n) 73Se reaction and via the reaction 74Ge (4He, 5n) 73Se, respectively [269] M. Jennewein, M. A. Lewis, D. Zhao, E. Tsyganov, N. Slavine, J. He, L. Watkins, V. D. Kodibagkar, S. O’Kelly, P. Kulkarni, P. P. Antich, A. Hermanne, F. Rösch, R. P. Mason, P. E. Thorpe. Clin. Cancer Res.14, 1377 (2008)..
Germanium chemistry resembles a heavier analogue of silicon chemistry, with notable stability of both +4 and +2 compounds. Germanium dioxide, GeO₂, is the principal oxide and occurs in quartz-like and rutile-like forms. Germanium tetrachloride, GeCl₄, is a volatile liquid used as an intermediate in purification and glass manufacture. Germanium monosulfide, GeS, and germanium disulfide, GeS₂, illustrate lower and higher oxidation-state chalcogenides. Germanes such as germane, GeH₄, are reactive hydrides used in deposition chemistry. Organogermanium compounds contain Ge–C bonds, but their chemistry is less commercially extensive than organosilicon chemistry.
See more information at the Germanium compound page.
Massive germanium metal is of low acute toxicity and is not considered a nutritional requirement for humans. Dusts and finely divided material can irritate the respiratory tract and should be controlled in industrial handling. Germane, GeH₄, is highly flammable and toxic, posing a significant gas-handling hazard. Germanium tetrachloride, GeCl₄, fumes in moist air and can form corrosive hydrogen chloride, HCl. Some soluble germanium compounds have caused kidney and nerve toxicity when ingested in inappropriate supplement use.
Germanium is a dispersed trace element in the crust and is enriched in some zinc ores, lignites, and coal ashes. In natural waters it commonly follows silica behavior because dissolved germanium species can resemble silicic acid in geochemical cycling. Weathering releases only small concentrations, and the element has no known essential biological function. Industrial releases are usually associated with mining, smelting, coal combustion residues, and processing of germanium-bearing intermediates.
Germanium supply is tied to by-product recovery, so availability depends strongly on zinc refining, processing of certain coal ashes, and the economics of collecting dilute streams. Concentrates are converted through intermediates such as germanium tetrachloride, GeCl₄, then hydrolyzed and reduced to high-purity metal or oxide. Demand is concentrated in fiber optics, infrared optics, polymerization catalysts, electronics, and space solar cells. Recycling from optical scrap, semiconductor material, and some catalysts is important because primary sources are geographically and geologically limited. Substitution is possible in some optical and electronic uses, but often with performance or design penalties.
The metal is found in
▸ argyrodite, a sulfide of germanium and silver;
▸ germanite, which contains 8 percent of the element;
▸ zinc ores;
▸ coal; and
▸ other minerals
The element is commercially obtained from the dust from smelters that process zinc ores. It is also recovered from combustion by-products of certain coals.
Germanium can be separated from other metals by fractional distillation of its volatile tetrachloride. These techniques permit the production of germanium of ultra-high purity.
Germanium is a minor cosmic element produced mainly by neutron-capture processes in evolved stars and supernova-related environments, with contributions from charged-particle reactions. It is far less abundant than silicon because heavier nuclei beyond iron-region seed patterns require less common nucleosynthetic pathways. In meteorites and planetary rocks it behaves partly as a moderately siderophile and chalcophile trace element, partitioning into metal and sulfide phases under suitable conditions.
- Germanium was predicted by Mendeleev as eka-silicon before it was isolated.
- Zone refining of germanium helped establish ultra-high-purity semiconductor practice.
- Germanium expands on freezing, as silicon and water do.
- Natural germanium contains five stable isotopes.
- GeO₂ can be reduced to the element with hydrogen in industrial purification.
Images
Propriétés
Propriétés physiques
- Rayon atomique (empirique)
- 125 pm Comparer : Rayon atomique (empirique) de tous les éléments →
- Rayon covalent
- 120 pm Comparer : Rayon covalent de tous les éléments →
- Rayon de van der Waals
- 211 pm Comparer : Rayon de van der Waals de tous les éléments →
- Rayon métallique
- 124 pm Comparer : Rayon métallique de tous les éléments →
- Masse volumique
- 5323,4 kg/m³ Comparer : Masse volumique de tous les éléments →
- Volume molaire
- 0,0136 L/mol
- Phase aux CNTP
- Solide Comparer : Phase aux CNTP de tous les éléments →
- Point de fusion
- 938,25 °C Comparer : Point de fusion de tous les éléments →
- Point d’ébullition
- 2832,85 °C Comparer : Point d’ébullition de tous les éléments →
- Conductivité thermique
- 60,2 W/(m·K) Comparer : Conductivité thermique de tous les éléments →
- Capacité thermique massique
- 0,32 J/(g·K) Comparer : Capacité thermique massique de tous les éléments →
- Capacité thermique molaire
- 23,222 J/(mol·K) Comparer : Capacité thermique molaire de tous les éléments →
- Structure cristalline
- Cubique de type diamant Comparer : Structure cristalline de tous les éléments →
Propriétés chimiques
- Électronégativité (Pauling)
- 2,01 Comparer : Électronégativité (Pauling) de tous les éléments →
- Électronégativité (Allen)
- 1,994
- Affinité électronique
- 1,232 eV
- Énergie d’ionisation (1re)
- 7,899435 eV Comparer : Énergie d’ionisation (1re) de tous les éléments →
- Énergie d’ionisation (2e)
- 15,934665 eV Comparer : Énergie d’ionisation (2e) de tous les éléments →
- Énergie d’ionisation (3e)
- 34,057717 eV Comparer : Énergie d’ionisation (3e) de tous les éléments →
- Énergie d’ionisation (4e)
- 45,715657 eV Comparer : Énergie d’ionisation (4e) de tous les éléments →
- Énergie d’ionisation (5e)
- 90,500312 eV Comparer : Énergie d’ionisation (5e) de tous les éléments →
- États d’oxydation
- −4, −3, −2, −1, 0, +1, +2, +3, +4 Comparer : États d’oxydation de tous les éléments →
- Électrons de valence
- 4 Comparer : Électrons de valence de tous les éléments →
- Configuration électronique
- [Ar] 4s2 3d10 4p2
Propriétés thermodynamiques
- Point critique (température)
- 9529 °C
- Enthalpie de fusion
- 0,38285744 eV Comparer : Enthalpie de fusion de tous les éléments →
- Enthalpie de vaporisation
- 3,420221 eV Comparer : Enthalpie de vaporisation de tous les éléments →
- Enthalpie de sublimation
- 3,907343 eV
- Enthalpie d’atomisation
- 3,907343 eV
- Enthalpie d’atomisation
- 3,855522 eV
Propriétés nucléaires
- Protons
- 32 Comparer : Protons de tous les éléments →
- Neutrons
- 42 Comparer : Neutrons de tous les éléments →
- Isotopes connus
- 33 Comparer : Isotopes connus de tous les éléments →
- Isotopes stables
- 4 Comparer : Isotopes stables de tous les éléments →
- Isotope le plus stable
- Ge-74
- Année de découverte
- 1886
Abondance
- Abondance (croûte terrestre)
- 1,5 mg/kg Comparer : Abondance (croûte terrestre) de tous les éléments →
- Abondance (océan)
- 5 × 10−5 mg/L Comparer : Abondance (océan) de tous les éléments →
Structure cristalline
- Paramètre de maille a
- 566 pm
Structure électronique
- Électrons par couche
- 2, 8, 18, 4 Comparer : Électrons par couche de tous les éléments →
Identifiants
- Numéro CAS
- 7440-56-4 Comparer : Numéro CAS de tous les éléments →
- Symbole de terme
- 3P0
- InChI
- InChI=1S/Ge
- Clé InChI
- GNPVGFCGXDBREM-UHFFFAOYSA-N
Configuration électronique Mesuré
Ge: 3d¹⁰ 4s² 4p²[Ar] 3d¹⁰ 4s² 4p²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p²Modèle atomique
Les isotopes diffèrent par leur nombre de neutrons, leur masse et leur stabilité — pas par la configuration électronique de l’atome neutre.
Modèle atomique schématique, non à l’échelle.
Empreinte atomique
Spectre d’émission / d’absorption
Distribution isotopique
| Nombre de masse | Masse atomique (u) | Abondance naturelle | Demi-vie |
|---|---|---|---|
| 70 Stable | 69,92424875 ± 0,0000009 | 20,5700% | Stable |
| 72 Stable | 71,922075826 ± 0,000000081 | 27,4500% | Stable |
| 73 Stable | 72,923458956 ± 0,000000061 | 7,7500% | Stable |
| 74 Stable | 73,921177761 ± 0,000000013 | 36,5000% | Stable |
Phase / État
Explication: 913,3 °C en dessous du point de fusion (938,25 °C)
Schématique, non à l’échelle
Points de transition de phase
Énergies de transition
Énergie nécessaire pour faire fondre 1 mol au point de fusion
Énergie nécessaire pour vaporiser 1 mol au point d’ébullition
Énergie nécessaire pour sublimer 1 mol au point de sublimation
Masse volumique
Dans les conditions standard
Dans les conditions standard
Données avancées
Spectres atomiques
Affichage de 10 sur 32. Tri par charge ionique croissante.
Raies répertoriées ?
| Ion | Charge | Nombre total de raies | Probabilités de transition | Désignations des niveaux |
|---|---|---|---|---|
| Ge I | 0 | 224 | 26 | 223 |
| Ge II | +1 | 149 | 20 | 149 |
| Ge III | +2 | 55 | 0 | 0 |
| Ge IV | +3 | 27 | 0 | 0 |
| Ge V | +4 | 37 | 0 | 0 |
Niveaux répertoriés ?
| Ion | Charge | Niveaux |
|---|---|---|
| Ge I | 0 | 621 |
| Ge II | +1 | 129 |
| Ge III | +2 | 48 |
| Ge IV | +3 | 55 |
| Ge V | +4 | 102 |
| Ge VI | +5 | 105 |
| Ge VII | +6 | 168 |
| Ge VIII | +7 | 2 |
| Ge IX | +8 | 2 |
| Ge X | +9 | 2 |
Rayons ioniques
| Charge | Coordinence | Spin | Rayon |
|---|---|---|---|
| +2 | 6 | N/D | 73 pm |
| +4 | 4 | N/D | 39 pm |
| +4 | 6 | N/D | 53 pm |
Composés
Isotopes (4)
| Nombre de masse | Masse atomique (u) | Abondance naturelle | Demi-vie | Mode de désintégration | |
|---|---|---|---|---|---|
| 70 Stable | 69,92424875 ± 0,0000009 | 20,5700% ± 0,2700% | Stable | stable | |
| 72 Stable | 71,922075826 ± 0,000000081 | 27,4500% ± 0,3200% | Stable | stable | |
| 73 Stable | 72,923458956 ± 0,000000061 | 7,7500% ± 0,1200% | Stable | stable | |
| 74 Stable | 73,921177761 ± 0,000000013 | 36,5000% ± 0,2000% | Stable | stable |
Raies spectrales
Affichage de 50 sur 57. Seules les raies spectrales dont l’intensité a été mesurée sont affichées par défaut.
| Longueur d’onde (nm) | Intensité | Degré d’ionisation | Type | Transition | Précision | Source | |
|---|---|---|---|---|---|---|---|
| 474.18054 nm | 1000 | Ge II | emission | 4s2.5p 2P* → 4s2.5d 2D | Mesurée | NIST | |
| 481.46084 nm | 1000 | Ge II | emission | 4s2.5p 2P* → 4s2.5d 2D | Mesurée | NIST | |
| 589.33885 nm | 1000 | Ge II | emission | 4s2.5s 2S → 4s2.5p 2P* | Mesurée | NIST | |
| 602.10412 nm | 500 | Ge II | emission | 4s2.5s 2S → 4s2.5p 2P* | Mesurée | NIST | |
| 517.86474 nm | 200 | Ge II | emission | 4s2.4d 2D → 4s2.4f 2F* | Mesurée | NIST | |
| 607.834 nm | 150 | Ge II | emission | 4s.4p.(3P*).5s 4P* → 4s.4p.(3P*).5p 4D | Mesurée | NIST | |
| 626.8068 nm | 150 | Ge II | emission | 4s2.4f 2F* → 4s2.6g 2G | Mesurée | NIST | |
| 513.17516 nm | 100 | Ge II | emission | 4s2.4d 2D → 4s2.4f 2F* | Mesurée | NIST | |
| 626.8341 nm | 100 | Ge II | emission | 4s2.4f 2F* → 4s2.6g 2G | Mesurée | NIST | |
| 633.63765 nm | 100 | Ge II | emission | 4s2.5p 2P* → 4s2.6s 2S | Mesurée | NIST | |
| 648.41813 nm | 100 | Ge II | emission | 4s2.5p 2P* → 4s2.6s 2S | Mesurée | NIST | |
| 628.34518 nm | 75 | Ge II | emission | 4s2.5d 2D → 4s2.6f 2F* | Mesurée | NIST | |
| 422.656259 nm | 70 | Ge I | emission | 4s2.4p2 1S → 4s2.4p.5s 1P* | Mesurée | NIST | |
| 482.40972 nm | 50 | Ge II | emission | 4s2.5p 2P* → 4s2.5d 2D | Mesurée | NIST | |
| 626.7136 nm | 50 | Ge II | emission | 4s2.5d 2D → 4s2.6f 2F* | Mesurée | NIST | |
| 678.0486 nm | 50 | Ge II | emission | 4s2.6p 2P* → 4s2.7d 2D | Mesurée | NIST | |
| 704.93692 nm | 50 | Ge II | emission | 4s.4p2 2D → 4s2.5p 2P* | Mesurée | NIST | |
| 384.50994 nm | 30 | Ge II | emission | 4s.4p2 4P → 4s2.5p 2P* | Mesurée | NIST | |
| 714.53898 nm | 30 | Ge II | emission | 4s.4p2 2D → 4s2.5p 2P* | Mesurée | NIST | |
| 494.12769 nm | 20 | Ge II | emission | 4s2.4d 2D → 4s2.6p 2P* | Mesurée | NIST | |
| 520.56488 nm | 20 | Ge II | emission | 4s2.4f 2F* → 4s2.7g 2G | Mesurée | NIST | |
| 696.63205 nm | 20 | Ge II | emission | 4s.4p2 2D → 4s2.5p 2P* | Mesurée | NIST | |
| 439.1656 nm | 15 | Ge II | emission | 4s2.4f 2F* → 4s2.9g 2G | Mesurée | NIST | |
| 520.58372 nm | 15 | Ge II | emission | 4s2.4f 2F* → 4s2.7g 2G | Mesurée | NIST | |
| 552.2987 nm | 15 | Ge II | emission | 4s2.6p 2P* → 4s2.8d 2D | Mesurée | NIST | |
| 439.179 nm | 10 | Ge II | emission | 4s2.4f 2F* → 4s2.9g 2G | Mesurée | NIST | |
| 466.2311 nm | 10 | Ge II | emission | 4s2.5d 2D → 4s2.8f 2F* | Mesurée | NIST | |
| 468.582849 nm | 10 | Ge I | emission | 4s2.4p2 1S → 4s2.4p.5s 3P* | Mesurée | NIST | |
| 493.40754 nm | 10 | Ge II | emission | 4s2.4d 2D → 4s2.6p 2P* | Mesurée | NIST | |
| 517.84615 nm | 10 | Ge II | emission | 4s2.4d 2D → 4s2.4f 2F* | Mesurée | NIST | |
| 569.19543 nm | 9 | Ge I | emission | 4s2.4p.5s 3P* → 4s2.4p.6p 3D | Mesurée | NIST | |
| 580.2093 nm | 9 | Ge I | emission | 4s2.4p.5s 1P* → 4s2.4p.6p 1D | Mesurée | NIST | |
| 556.47408 nm | 8 | Ge I | emission | 4s2.4p.5s 3P* → 4s2.4p.6p 3S | Mesurée | NIST | |
| 560.70101 nm | 8 | Ge I | emission | 4s2.4p.5s 3P* → 4s2.4p.6p 3P | Mesurée | NIST | |
| 565.596 nm | 8 | Ge I | emission | 4s2.4p.5s 3P* → 4s2.4p.6p 3D | Mesurée | NIST | |
| 562.14256 nm | 7 | Ge I | emission | 4s2.4p.5s 3P* → 4s2.4p.6p 1P | Mesurée | NIST | |
| 733.0383 nm | 7 | Ge I | emission | 4s2.4p.5p 1P → 4s2.4p.7d (1/2,3/2)* | Mesurée | NIST | |
| 738.4208 nm | 7 | Ge I | emission | 4s2.4p.5p 3D → 4s2.4p.8s (1/2,1/2)* | Mesurée | NIST | |
| 526.58915 nm | 6 | Ge I | emission | 4s2.4p.5s 3P* → 4s2.4p.6p 3P | Mesurée | NIST | |
| 551.32634 nm | 6 | Ge I | emission | 4s2.4p.5s 3P* → 4s2.4p.6p 1D | Mesurée | NIST | |
| 561.61353 nm | 6 | Ge I | emission | 4s2.4p.5s 3P* → 4s2.4p.6p 3P | Mesurée | NIST | |
| 566.4226 nm | 6 | Ge I | emission | 4s2.4p.5s 1P* → 4s2.4p.6p 1S | Mesurée | NIST | |
| 570.17765 nm | 6 | Ge I | emission | 4s2.4p.5s 3P* → 4s2.4p.6p 1P | Mesurée | NIST | |
| 580.1029 nm | 6 | Ge I | emission | 4s2.4p.5s 3P* → 4s2.4p.6p 3D | Mesurée | NIST | |
| 655.74883 nm | 6 | Ge I | emission | 4s2.4p.5s 1P* → 4s2.4p.6p 3D | Mesurée | NIST | |
| 713.0126 nm | 6 | Ge I | emission | 4s2.4p.5p 3D → 4s2.4p.7d (3/2,5/2)* | Mesurée | NIST | |
| 740.2648 nm | 6 | Ge I | emission | 4s2.4p.5p 1P → 4s2.4p.6d (3/2,3/2)* | Mesurée | NIST | |
| 518.4103 nm | 5 | Ge II | emission | 4s2.5d 2D → 4s2.7f 2F* | Mesurée | NIST | |
| 566.4842 nm | 5 | Ge I | emission | 4s2.4p.5s 3P* → 4s2.4p.(2P*<1/2>).4f 2[7/2] | Mesurée | NIST | |
| 571.78769 nm | 5 | Ge I | emission | 4s2.4p.5s 3P* → 4s2.4p.6p 3D | Mesurée | NIST |
Propriétés étendues
Rayons covalents (données étendues)
- Rayon covalent (Pyykkö)
- 121 pm
- Rayon covalent (Pyykkö, liaison double)
- 111 pm
- Rayon covalent (Pyykkö, liaison triple)
- 114 pm
Rayons de van der Waals
- Truhlar
- 211 pm
- Batsanov
- 210 pm
- Alvarez
- 229 pm
- UFF
- 428 pm
- MM3
- 244 pm
- Dreiding
- 427 pm
Rayons atomiques et métalliques
- Rayon atomique (Rahm)
- 234 pm
- Rayon métallique (C12)
- 144 pm
Échelles de numérotation
- Mendeleev
- 89
- Pettifor
- 84
- Glawe
- 84
Échelles d’électronégativité
- Ghosh
- 0
- Miedema
- 5
- Gunnarsson–Lundqvist
- 5
- Robles–Bartolotti
- 4
Polarisabilité et dispersion
- Polarisabilité dipolaire
- 40 a.u.
- Polarisabilité dipolaire (incertitude)
- 1 a.u.
- C₆
- 354 Ha·Bohr6
- C₆ (Gould–Bučko)
- 365 Ha·Bohr6
Paramètres de Miedema
- Volume molaire de Miedema
- 9,87 cm3/mol
- Densité électronique de Miedema
- 3
Risque d’approvisionnement et économie
- Concentration de la production
- 67
- Risque relatif d’approvisionnement
- 8
- Stabilité politique (principal producteur)
- 24
Transitions de phase et allotropes
| Point de fusion | 1211,4 K |
| Point d’ébullition | 3106,15 K |
| Point critique (température) | 9802,15 K |
Catégories d’états d’oxydation
Données de référence avancées
Constantes d’écran (8)
| n | Orbitale | σ |
|---|---|---|
| 1 | s | 0,7063 |
| 2 | p | 3,9178 |
| 2 | s | 8,6352 |
| 3 | d | 15,7487 |
| 3 | p | 14,9864 |
| 3 | s | 14,2103 |
| 4 | p | 25,2196 |
| 4 | s | 23,9564 |
Détail des rayons cristallins (3)
| Charge | CN | Spin | rcrystal (pm) | Origine |
|---|---|---|---|---|
| 2 | VI | 87 | Ahrens (1952) ionic radius, | |
| 4 | IV | 53 | ||
| 4 | VI | 67 | from r^3 vs V plots, |
Modes de désintégration des isotopes (50)
| Isotope | Mode | Intensité |
|---|---|---|
| 58 | 2p | — |
| 59 | B+ | 100% |
| 59 | B+p | 93% |
| 59 | 2p | 0,2% |
| 60 | B+ | 100% |
| 60 | B+p | 100% |
| 60 | 2p | 14% |
| 61 | B+ | 100% |
| 61 | B+p | 87% |
| 62 | B+ | 100% |
Facteurs de diffusion des rayons X (506)
| Énergie (eV) | f₁ | f₂ |
|---|---|---|
| 10 | — | 3,01183 |
| 10,1617 | — | 3,05548 |
| 10,3261 | — | 3,09976 |
| 10,4931 | — | 3,14468 |
| 10,6628 | — | 3,19025 |
| 10,8353 | — | 3,21825 |
| 11,0106 | — | 3,20755 |
| 11,1886 | — | 3,19689 |
| 11,3696 | — | 3,18626 |
| 11,5535 | — | 3,17568 |
Données complémentaires
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
1.5 milligrams per kilogram
Références (1)
- [5] Germanium https://education.jlab.org/itselemental/ele032.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
5×10-5 milligrams per liter
Références (1)
- [5] Germanium https://education.jlab.org/itselemental/ele032.html
Sources
Sources of this element.
The metal is found in
▸ argyrodite, a sulfide of germanium and silver;
▸ germanite, which contains 8 percent of the element;
▸ zinc ores;
▸ coal; and
▸ other minerals
The element is commercially obtained from the dust from smelters that process zinc ores. It is also recovered from combustion by-products of certain coals.
Germanium can be separated from other metals by fractional distillation of its volatile tetrachloride. These techniques permit the production of germanium of ultra-high purity.
Références (1)
- [6] Germanium https://periodic.lanl.gov/32.shtml
Références
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Germanium.
The element property data was retrieved from publications.