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Sg 106

Seaborgium (Sg)

transition-metal
Période: 7 Groupe: 6 Bloc: d

Solid

Masse atomique relative standard

[271]

Configuration électronique

[Rn] 7s2 5f14 6d4

Point de fusion

N/D

Point d’ébullition

N/D

Masse volumique

3,5e+4 kg/m³

États d’oxydation

+3, +4, +5, +6

Électronégativité (Pauling)

N/D

Énergie d’ionisation (1re)

7,8 eV

Année de découverte

1974

Rayon atomique

132 pm

Détails

Origine du nom Named in honor of Glenn Seaborg, American physical chemist known for research on transuranium elements.
Pays de découverte USSR/United States
Découvreurs Soviet Nuclear Research/ U. of Cal at Berkeley

Seaborgium is a synthetic transactinide element in group 6, below tungsten. All confirmed isotopes are radioactive and short-lived, so its chemistry is studied atom by atom rather than in bulk. Experiments show that seaborgium behaves broadly as a heavier homolog of molybdenum and tungsten, with a stable +6 oxidation state in suitable compounds, while relativistic effects modify details of its volatility and complex formation.

Seaborgium does not occur naturally in the Earth’s crust. In 1974, seaborgium was first synthesized by Albert Ghiorso and his team at the University of California in Berkeley using the nuclear reaction 249Cf (18O, 4n) 263Sg. The element is named for Glenn T. Seaborg (Fig. IUPAC.106.1), who synthesized a number of trans-uranium elements [634], [648].

Seaborgium has no commercial applications. However, 265Sg was one of the decay products used to confirm the synthesis of copernicium in a particle accelerator experiment.

Seaborgium is named after Glenn Seaborg.

Seaborgium was first produced by a team of scientists led by Albert Ghiorso working at the Lawrence Berkeley Laboratory in Berkeley, California, in 1974. They created seaborgium by bombarding atoms of californium-249 with ions of oxygen-18 using a machine called the Super-Heavy Ion Linear Accelerator. The collision produced atoms of seaborgium-263 and four free neutrons. Seaborgium-263 is an isotope of seaborgium with a half-life of about 1 second. Three months before the Berkeley group announced their discovery, a team of scientists working at the Joint Institute for Nuclear Research in Dubna, Russia, claimed to have produced seaborgium. Their method involved bombarding atoms of lead-207 and lead-208 with ions of chromium-54 with a device called a cyclotron. They believed that they had produced atoms of seaborgium-259. The Berkeley group's work was confirmed in 1993 and they were credited with the discovery. Seaborgium's most stable isotope, seaborgium-271, has a half-life of about 2.4 minutes. It decays into rutherfordium-267 through alpha decay or decays through spontaneous fission..

IIn June 1974, members of the Joint Institute for Nuclear Research in Dubna, U.S.S.R., reported their discovery of Element 106, which they reported to have synthesized. Glenn Seaborg was part of this group, and the element was named in his honor.

In September 1974, workers of the Lawrence Berkeley and Livermore Laboratories also claimed creation Element 106 "without any scientific doubt." The LBL and LLL Group used the Super HILAC to accelerate 18O ions onto a 249Cf target.

Element 106 was created by the reaction 249Cf(18O, 4N)263X, which decayed by alpha emission to rutherfordium, and then by alpha emission to nobelium, which in turn further decayed by alpha between daughter and granddaughter. The element so identified had alpha energies of 9.06 and 9.25 MeV with a half-life of 0.9 +/- 0.2 s.

At Dubna, 280-MeV ions of 54Cr from the 310-cm cyclotron were used to strike targets of 206Pb, 207Pb, and 208Pb, in separate runs. Foils exposed to a rotating target disc were used to detect spontaneous fission activities. The foils were etched and examined microscopically to detect the number of fission tracks and the half-life of the fission activity. Other experiments were made to aid in confirmation of the discovery.

Images

Propriétés

Propriétés physiques

Rayon atomique (empirique)
132 pm Comparer : Rayon atomique (empirique) de tous les éléments →
Masse volumique
3,5 × 104 kg/m³ Comparer : Masse volumique de tous les éléments →

Propriétés chimiques

Affinité électronique
0,85 eV
Énergie d’ionisation (1re)
7,8 eV Comparer : Énergie d’ionisation (1re) de tous les éléments →
Énergie d’ionisation (2e)
17,100059 eV Comparer : Énergie d’ionisation (2e) de tous les éléments →
Énergie d’ionisation (3e)
25,800089 eV Comparer : Énergie d’ionisation (3e) de tous les éléments →
Énergie d’ionisation (4e)
35,500122 eV Comparer : Énergie d’ionisation (4e) de tous les éléments →
Énergie d’ionisation (5e)
47,200162 eV Comparer : Énergie d’ionisation (5e) de tous les éléments →
États d’oxydation
+3, +4, +5, +6 Comparer : États d’oxydation de tous les éléments →
Électrons de valence
6 Comparer : Électrons de valence de tous les éléments →
Configuration électronique
[Rn] 7s2 5f14 6d4

Propriétés thermodynamiques

N/D

Propriétés nucléaires

Protons
106 Comparer : Protons de tous les éléments →
Neutrons
163 Comparer : Neutrons de tous les éléments →
Isotopes connus
16 Comparer : Isotopes connus de tous les éléments →
Isotopes stables
0 Comparer : Isotopes stables de tous les éléments →
Nombre de masse (isotope le plus stable)
271
Isotope le plus stable
Sg-269
Année de découverte
1974

Abondance

N/D

Structure cristalline

N/D

Structure électronique

Électrons par couche
2, 8, 18, 32, 32, 12, 2 Comparer : Électrons par couche de tous les éléments →

Identifiants

Numéro CAS
54038-81-2 Comparer : Numéro CAS de tous les éléments →
Symbole de terme
0
InChI
InChI=1S/Sg
Clé InChI
VAOUCABZIBBBJH-UHFFFAOYSA-N

Configuration électronique Prédit

Charge ionique
Protons 106
Électrons 106
Charge Neutre
Configuration Sg: 5f¹⁴ 6d⁴ 7s²
Configuration électronique
Prédit
[Rn] 5f¹⁴ 6d⁴ 7s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 5f¹⁴ 6d⁴ 7s²
Diagramme d’orbitales
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
10/10
6p
6/6
7s
2/2
5f
14/14
6d
4/10 4↑
Nombre total d’électrons: 106 Non appariés: 4 ?

Modèle atomique

Protons 106
Neutrons 157
Électrons 106
Nombre de masse 263
Stabilité Radioactif

Les isotopes diffèrent par leur nombre de neutrons, leur masse et leur stabilité — pas par la configuration électronique de l’atome neutre.

Modèle atomique schématique, non à l’échelle.

Empreinte atomique

Spectre d’émission / d’absorption

0 / 0 (0 0 avec intensité)
Mesuré
Émission Visible : 380–750 nm

Distribution isotopique

Aucun isotope stable.

Nombre de masseMasse atomique (u)Abondance naturelleDemi-vie
263 Radioactif263,11829 ± 0,0001N/D940 ms
259 Radioactif259,1144 ± 0,00013N/D402 ms
266 Radioactif266,12198 ± 0,00026N/D390 ms
261 Radioactif261,115949 ± 0,00002N/D183 ms
264 Radioactif264,11893 ± 0,0003N/D78 ms
Mesuré

Phase / État

1 atm / 101,325 kPa Prédit
Inconnue 25 °C (298,15 K)
0 K Température actuelle: 25 °C 6000 K

Données de phase ou d’état indisponibles

Spectres atomiques

Affichage de 10 sur 95. Tri par charge ionique croissante.

Niveaux répertoriés ?

IonChargeNiveaux
Sg I 02
Sg II +12
Sg III +22
Sg IV +32
Sg V +42
Sg VI +52
Sg VII +62
Sg VIII +72
Sg IX +82
Sg X +92
Niveaux répertoriés par le NIST →
106 Sg 271

Seaborgium — Visualiseur d’orbitales atomiques

[Rn]7s25f146d4
Niveaux d’énergie 2 8 18 32 32 12 2
États d’oxydation +3, +4, +5, +6
HOMO 6d n=6 · l=2 · m=-2
Seaborgium — Aperçu du visualiseur d’orbitales atomiques
Three.js se charge uniquement à la demande
106 Sg 271

Seaborgium — Visualiseur de structure cristalline

Données de phase ou d’état indisponibles

Composés

Sg
269,128 u

Isotopes (5)

Nombre de masseMasse atomique (u)Abondance naturelleDemi-vieMode de désintégration
263 Radioactif263,11829 ± 0,0001N/D940 ms
α =87±0.8%SF =13±0.8%
259 Radioactif259,1144 ± 0,00013N/D402 ms
α ≈100%SF ?β+ ?
266 Radioactif266,12198 ± 0,00026N/D390 ms
SF>90%
261 Radioactif261,115949 ± 0,00002N/D183 ms
α =98.1±0.4%β+ =1.3±0.3%SF =0.6±0.2%
264 Radioactif264,11893 ± 0,0003N/D78 ms
SF>80% α ?
263 Radioactif
Masse atomique (u) 263,11829 ± 0,0001
Abondance naturelle N/D
Demi-vie 940 ms
Mode de désintégration
α =87±0.8%SF =13±0.8%
259 Radioactif
Masse atomique (u) 259,1144 ± 0,00013
Abondance naturelle N/D
Demi-vie 402 ms
Mode de désintégration
α ≈100%SF ? +1
266 Radioactif
Masse atomique (u) 266,12198 ± 0,00026
Abondance naturelle N/D
Demi-vie 390 ms
Mode de désintégration
SF>90%
261 Radioactif
Masse atomique (u) 261,115949 ± 0,00002
Abondance naturelle N/D
Demi-vie 183 ms
Mode de désintégration
α =98.1±0.4%β+ =1.3±0.3% +1
264 Radioactif
Masse atomique (u) 264,11893 ± 0,0003
Abondance naturelle N/D
Demi-vie 78 ms
Mode de désintégration
SF>80% α ?

Propriétés étendues

Rayons covalents (données étendues)

Rayon covalent (Pyykkö)
143 pm
Rayon covalent (Pyykkö, liaison double)
128 pm
Rayon covalent (Pyykkö, liaison triple)
121 pm

Échelles de numérotation

Mendeleev
54

Polarisabilité et dispersion

Polarisabilité dipolaire
40 a.u.
Polarisabilité dipolaire (incertitude)
4 a.u.

Catégories d’états d’oxydation

+3 extended
+6 extended
+5 extended
+4 extended

Données de référence avancées

Modes de désintégration des isotopes (32)
IsotopeModeIntensité
258SF100%
258A—
259A100%
259SF—
259B+—
260SF71%
260A29%
261A98,1%
261B+1,3%
261SF0,6%

Données complémentaires

Références

(8)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Sg

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Seaborgium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

Note sur la licence: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Seaborgium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

Note sur la licence: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Seaborgium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Seaborgium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Seaborgium

This section provides all form of data related to element Seaborgium.

Dernière mise à jour:

Données vérifiées:

Le contenu est vérifié au regard des dernières données scientifiques.