Nobelium (No)
actinideSolid
Masse atomique relative standard
[259]Configuration électronique
[Rn] 7s2 5f14Point de fusion
826,85 °CPoint d’ébullition
N/DMasse volumique
9900 kg/m³États d’oxydation
+2, +3Électronégativité (Pauling)
1,3Énergie d’ionisation (1re)
6,62621 eVAnnée de découverte
1957Rayon atomique
N/DDétails
Nobelium is a synthetic actinide with atomic number 102. It is produced only in particle-accelerator experiments and is studied in atom-at-a-time quantities. Its longest-lived confirmed isotopes have half-lives of only minutes, so no macroscopic sample or ordinary material application exists. Chemically, nobelium is notable because the +2 oxidation state is unusually stable for an actinide, in contrast to the more common +3 state of many neighboring elements.
Nobelium does not occur naturally in the Earth’s crust. It was first synthesized in 1966 by Russian scientists from the Joint Institute for Nuclear Research (JINR) in Dubna, Russia under Georgi Flerov. Earlier claims to have synthesized “nobelium” beginning in 1957 were shown to be erroneous. This element was originally named for Alfred Nobel (Fig. IUPAC.102.1), the inventor of dynamite and founder of the Nobel prizes. The name was later retained because of its widespread use throughout the scientific literature [636], [638]. There are no uses for isotopes of nobelium outside of scientific research.
Nobelium is named after Alfred Nobel.
In 1957, a group of scientists working at the Nobel Institute of Physics in Stockhlom, Sweden, announced the discovery of a new element. They produced this new element, which they named nobelium, by bombarding a target of curium-244 with ions of carbon-13 with a device called a cyclotron. The isotope they created had a half-life of 10 minutes. In 1958, another group of scientists, Albert Ghiorso, Glenn T. Seaborg, Torbørn Sikkeland and John R. Walton, working at the Lawrence Radiation Laboratory in Berkeley, California, attempted to confirm the Nobel Institute's discovery. They were unable to produce any isotope of nobelium with a half-life of 10 minutes, but were able to produce nobelium-254, with a half-life of three seconds, by bombarding curium-246 with carbon-12. A third group, working at the Joint Institute for Nuclear Research in Dubna, Russia, also could not duplicate the Nobel Institute's work but were able to confirm the Berkeley group's work. Credit for discovering nobelium was eventually given to the scientists working at Lawrence Radiation Laboratory, who decided to keep the name nobelium. Today, the Lawrence Radiation Laboratory is known as the Lawrence Berkeley Laboratory. Nobelium's most stable isotope, nobelium-259, has a half-life of about 58 minutes. It decays into fermium-255 through alpha decay, into mendelevium-259 through electron capture or through spontaneous fission.
Named after Alfred Nobel, inventor of dynamite. Nobelium was unambiguously discovered and identified in April 1958 at Berkeley by A. Ghiorso, T. Sikkeland, J.R. Walton, and G.T. Seaborg, who used a new double-recoil technique. A heavy-ion linear accelerator (HILAC) was used to bombard a thin target of curium (95%244Cm and 4.5% 246Cm) with 12C ions to produce 102No according to the 246Cm(12C, 4n) reaction.
In 1957 workers in the United States, Britain, and Sweden announced the discovery of an isotope of element 102 with a 10-minute half-life at 8.5 MeV, as a result of bombarding 244Cm with 13C nuclei. On the basis of this experiment, the name nobelium was assigned and accepted by the Commission on Atomic Weights of the International Union of Pure and Applied Chemistry.
The acceptance of the name was premature because both Russian and American efforts now completely rule out the possibility of any isotope of Element 102 having a half-life of 10 min in the vicinity of 8.5 MeV. Early work in 1957 on the search for this element, in Russia at the Kurchatov Institute, was marred by the assignment of 8.9 +/- 0.4 MeV alpha radiation with a half-life of 2 to 40 sec, which was too indefinite to support discovery claims.
Confirmatory experiments at Berkeley in 1966 have shown the existence of 254102 with a 55-s half-life, 252102 with a 2.3-s half-life, and 257102 with a 23-s half-life.
Following tradition giving the right to name an element to the discoverer(s), the Berkeley group in 1967, suggested that the hastily given name nobelium along with the symbol No , be retained.
The bulk appearance of nobelium is unknown, because it has never been isolated as a visible sample. Metallic nobelium is expected to be a dense, silvery actinide metal by analogy with neighboring elements, but this is a prediction rather than an observed property.
Nobelium has no practical use outside scientific research. Individual atoms are produced to study heavy-element nuclear stability, decay chains, and relativistic effects in actinide chemistry. Its isotopes have also served as links in identifying the decay products of heavier synthetic elements. These uses rely on rapid radiochemical separation and radiation detection, not on bulk nobelium metal or compounds.
Since only tiny amounts of nobelium have ever been produced, there are currently no uses for it outside of basic scientific research.
Nobelium chemistry has been examined mainly in aqueous tracer experiments. The divalent ion No²⁺ is the best-established chemically distinctive form and behaves in some separations more like alkaline earth ions than typical trivalent actinides. The trivalent ion No³⁺ is also known, but it is less favored in reducing aqueous systems. Specific bulk compounds such as nobelium(II) chloride, NoCl₂, or nobelium(III) oxide, No₂O₃, have not been isolated as macroscopic materials; their properties are inferred from trace chemistry and theory.
See more information at the Nobelium compound page.
All known nobelium isotopes are radioactive, and several decay by alpha emission or spontaneous fission. The element is made in quantities far too small to create ordinary chemical toxicity hazards outside specialized laboratories, but radiological precautions are essential during production and detection work. Safety considerations are isotope-specific because half-lives and decay modes vary widely.
Nobelium has no confirmed natural environmental reservoir. Any atoms produced on Earth are artificial and decay rapidly compared with geological or ecological timescales. Because only atom-scale amounts are generated in shielded research facilities, nobelium has no known role in biogeochemical cycles and no observed environmental transport behavior as a bulk contaminant.
Nobelium is not a traded commodity and has no commercial supply chain. It is made by bombarding heavy actinide targets, commonly curium or californium isotopes, with accelerated light ions under conditions optimized for a desired isotope. Production yields are extremely small, and separation must occur quickly because of radioactive decay. The limiting factors are accelerator access, rare target materials, radiochemical expertise, and detector time rather than market demand, recycling, or substitution.
Made by bombarding curium with carbon-13
Nobelium is not expected to have a persistent cosmic abundance. Its known isotopes are too short-lived to survive from stellar nucleosynthesis to the present, and no stable isotope is known. If formed transiently in extreme neutron-rich events or by artificial nuclear reactions, nobelium would decay rapidly into lighter nuclei.
- Nobelium was named for Alfred Nobel, the inventor and industrial chemist associated with the Nobel Prizes.
- The isotope ²⁵⁹No is among the longest-lived known nobelium isotopes, with a half-life of about an hour.
- Nobelium helped show that the +2 state can become strongly stabilized late in the actinide series.
- Most nobelium experiments detect decay events from individual atoms rather than weighing a sample.
Images
Propriétés
Propriétés physiques
- Rayon de van der Waals
- 246 pm Comparer : Rayon de van der Waals de tous les éléments →
- Masse volumique
- 9900 kg/m³ Comparer : Masse volumique de tous les éléments →
- Phase aux CNTP
- Solide Comparer : Phase aux CNTP de tous les éléments →
- Point de fusion
- 826,85 °C Comparer : Point de fusion de tous les éléments →
Propriétés chimiques
- Électronégativité (Pauling)
- 1,3 Comparer : Électronégativité (Pauling) de tous les éléments →
- Affinité électronique
- -2,36 eV (valeur négative — l'atome ne devrait pas lier d'électron supplémentaire)
- Énergie d’ionisation (1re)
- 6,62621 eV Comparer : Énergie d’ionisation (1re) de tous les éléments →
- Énergie d’ionisation (2e)
- 12,930045 eV Comparer : Énergie d’ionisation (2e) de tous les éléments →
- Énergie d’ionisation (3e)
- 25,800089 eV Comparer : Énergie d’ionisation (3e) de tous les éléments →
- Énergie d’ionisation (4e)
- 41,500143 eV Comparer : Énergie d’ionisation (4e) de tous les éléments →
- Énergie d’ionisation (5e)
- 60,000207 eV Comparer : Énergie d’ionisation (5e) de tous les éléments →
- États d’oxydation
- +2, +3 Comparer : États d’oxydation de tous les éléments →
- Électrons de valence
- 3 Comparer : Électrons de valence de tous les éléments →
- Configuration électronique
- [Rn] 7s2 5f14
Propriétés thermodynamiques
- Enthalpie de sublimation
- 4,042079 eV
- Enthalpie d’atomisation
- 4,042079 eV
Propriétés nucléaires
- Protons
- 102 Comparer : Protons de tous les éléments →
- Neutrons
- 159 Comparer : Neutrons de tous les éléments →
- Isotopes connus
- 17 Comparer : Isotopes connus de tous les éléments →
- Isotopes stables
- 0 Comparer : Isotopes stables de tous les éléments →
- Nombre de masse (isotope le plus stable)
- 259
- Isotope le plus stable
- No-261
- Année de découverte
- 1957
Abondance
N/D
Structure cristalline
N/D
Structure électronique
- Électrons par couche
- 2, 8, 18, 32, 32, 8, 2 Comparer : Électrons par couche de tous les éléments →
Identifiants
- Numéro CAS
- 10028-14-5 Comparer : Numéro CAS de tous les éléments →
- Symbole de terme
- 1S0
- InChI
- InChI=1S/No
- Clé InChI
- ORQBXQOJMQIAOY-UHFFFAOYSA-N
Configuration électronique Mesuré
No: 5f¹⁴ 7s²[Rn] 5f¹⁴ 7s²1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 5f¹⁴ 7s²Modèle atomique
Les isotopes diffèrent par leur nombre de neutrons, leur masse et leur stabilité — pas par la configuration électronique de l’atome neutre.
Modèle atomique schématique, non à l’échelle.
Empreinte atomique
Spectre d’émission / d’absorption
Distribution isotopique
Aucun isotope stable.
| Nombre de masse | Masse atomique (u) | Abondance naturelle | Demi-vie |
|---|---|---|---|
| 251 Radioactif | 251,08894 ± 0,00012 | N/D | 800 ms |
| 260 Radioactif | 260,10264 ± 0,00022 | N/D | 106 ms |
| 259 Radioactif | 259,10103 ± 0,00011 | N/D | 58 minutes |
| 249 Radioactif | 249,0878 ± 0,0003 | N/D | 57 us |
| 254 Radioactif | 254,090956 ± 0,000011 | N/D | 51.2 secondes |
Phase / État
Explication: 801,9 °C en dessous du point de sublimation (826,85 °C)
Schématique, non à l’échelle
Points de transition de phase
Énergies de transition
Énergie nécessaire pour sublimer 1 mol au point de sublimation
Masse volumique
Dans les conditions standard
Dans les conditions standard
Spectres atomiques
Affichage de 10 sur 102. Tri par charge ionique croissante.
Niveaux répertoriés ?
| Ion | Charge | Niveaux |
|---|---|---|
| No I | 0 | 2 |
| No II | +1 | 2 |
| No III | +2 | 2 |
| No IV | +3 | 2 |
| No V | +4 | 2 |
| No VI | +5 | 2 |
| No VII | +6 | 2 |
| No VIII | +7 | 2 |
| No IX | +8 | 2 |
| No X | +9 | 2 |
Données de structure cristalline indisponibles
Rayons ioniques
| Charge | Coordinence | Spin | Rayon |
|---|---|---|---|
| +2 | 6 | N/D | 110.00000000000001 pm |
| +3 | 9 | N/D | 108.5 pm |
Composés
Isotopes (5)
Ten isotopes are now recognized, one of which 255102 has a half-life of 3 minutes.
| Nombre de masse | Masse atomique (u) | Abondance naturelle | Demi-vie | Mode de désintégration | |
|---|---|---|---|---|---|
| 251 Radioactif | 251,08894 ± 0,00012 | N/D | 800 ms | α =83±1.6%β+ ?SF<0.3% | |
| 260 Radioactif | 260,10264 ± 0,00022 | N/D | 106 ms | SF =100% | |
| 259 Radioactif | 259,10103 ± 0,00011 | N/D | 58 minutes | α =75±0.4%ε =25±0.4%SF<10% | |
| 249 Radioactif | 249,0878 ± 0,0003 | N/D | 57 us | β+ ?α ? | |
| 254 Radioactif | 254,090956 ± 0,000011 | N/D | 51.2 secondes | α =90±0.1%β+ =10±0.1%SF =0.17±0.2% |
Propriétés étendues
Rayons covalents (données étendues)
- Rayon covalent (Pyykkö)
- 176 pm
Rayons de van der Waals
- UFF
- 324,8 pm
Échelles de numérotation
- Mendeleev
- 40
- Pettifor
- 35
- Glawe
- 46
Échelles d’électronégativité
- Ghosh
- 0
Polarisabilité et dispersion
- Polarisabilité dipolaire
- 110 a.u.
- Polarisabilité dipolaire (incertitude)
- 6 a.u.
Transitions de phase et allotropes
| Point de fusion | 1100,15 K |
Catégories d’états d’oxydation
Données de référence avancées
Détail des rayons cristallins (2)
| Charge | CN | Spin | rcrystal (pm) | Origine |
|---|---|---|---|---|
| 2 | VI | 124 | estimated, | |
| 3 | IX | — | 122,5 |
Modes de désintégration des isotopes (39)
| Isotope | Mode | Intensité |
|---|---|---|
| 248 | SF | — |
| 249 | B+ | — |
| 249 | A | — |
| 250 | SF | 100% |
| 250 | A | — |
| 250 | B+ | — |
| 251 | A | 83% |
| 251 | B+ | — |
| 251 | SF | 0,3% |
| 252 | A | 67,6% |
Données complémentaires
Estimated Crustal Abundance
The estimated element abundance in the earth's crust.
Not Applicable
Références (1)
- [5] Nobelium https://education.jlab.org/itselemental/ele102.html
Estimated Oceanic Abundance
The estimated element abundance in the earth's oceans.
Not Applicable
Références (1)
- [5] Nobelium https://education.jlab.org/itselemental/ele102.html
Références
(9)
Data deposited in or computed by PubChem
The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.
Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.
The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.
Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/
The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.
The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database
This section provides all form of data related to element Nobelium.
The element property data was retrieved from publications.
