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No 102

Nobelium (No)

actinide
Période: 7 Bloc: f

Solid

Masse atomique relative standard

[259]

Configuration électronique

[Rn] 7s2 5f14

Point de fusion

826,85 °C

Point d’ébullition

N/D

Masse volumique

9900 kg/m³

États d’oxydation

+2, +3

Électronégativité (Pauling)

1,3

Énergie d’ionisation (1re)

6,62621 eV

Année de découverte

1957

Rayon atomique

N/D

Détails

Origine du nom Named in honor of Alfred Nobel, who invented dynamite and founded Nobel prize.
Pays de découverte Sweden
Découvreurs Nobel Institute for Physics

Nobelium is a synthetic actinide with atomic number 102. It is produced only in particle-accelerator experiments and is studied in atom-at-a-time quantities. Its longest-lived confirmed isotopes have half-lives of only minutes, so no macroscopic sample or ordinary material application exists. Chemically, nobelium is notable because the +2 oxidation state is unusually stable for an actinide, in contrast to the more common +3 state of many neighboring elements.

Nobelium does not occur naturally in the Earth’s crust. It was first synthesized in 1966 by Russian scientists from the Joint Institute for Nuclear Research (JINR) in Dubna, Russia under Georgi Flerov. Earlier claims to have synthesized “nobelium” beginning in 1957 were shown to be erroneous. This element was originally named for Alfred Nobel (Fig. IUPAC.102.1), the inventor of dynamite and founder of the Nobel prizes. The name was later retained because of its widespread use throughout the scientific literature [636], [638]. There are no uses for isotopes of nobelium outside of scientific research.

Nobelium is named after Alfred Nobel.

In 1957, a group of scientists working at the Nobel Institute of Physics in Stockhlom, Sweden, announced the discovery of a new element. They produced this new element, which they named nobelium, by bombarding a target of curium-244 with ions of carbon-13 with a device called a cyclotron. The isotope they created had a half-life of 10 minutes. In 1958, another group of scientists, Albert Ghiorso, Glenn T. Seaborg, Torbørn Sikkeland and John R. Walton, working at the Lawrence Radiation Laboratory in Berkeley, California, attempted to confirm the Nobel Institute's discovery. They were unable to produce any isotope of nobelium with a half-life of 10 minutes, but were able to produce nobelium-254, with a half-life of three seconds, by bombarding curium-246 with carbon-12. A third group, working at the Joint Institute for Nuclear Research in Dubna, Russia, also could not duplicate the Nobel Institute's work but were able to confirm the Berkeley group's work. Credit for discovering nobelium was eventually given to the scientists working at Lawrence Radiation Laboratory, who decided to keep the name nobelium. Today, the Lawrence Radiation Laboratory is known as the Lawrence Berkeley Laboratory. Nobelium's most stable isotope, nobelium-259, has a half-life of about 58 minutes. It decays into fermium-255 through alpha decay, into mendelevium-259 through electron capture or through spontaneous fission.

Named after Alfred Nobel, inventor of dynamite. Nobelium was unambiguously discovered and identified in April 1958 at Berkeley by A. Ghiorso, T. Sikkeland, J.R. Walton, and G.T. Seaborg, who used a new double-recoil technique. A heavy-ion linear accelerator (HILAC) was used to bombard a thin target of curium (95%244Cm and 4.5% 246Cm) with 12C ions to produce 102No according to the 246Cm(12C, 4n) reaction.

In 1957 workers in the United States, Britain, and Sweden announced the discovery of an isotope of element 102 with a 10-minute half-life at 8.5 MeV, as a result of bombarding 244Cm with 13C nuclei. On the basis of this experiment, the name nobelium was assigned and accepted by the Commission on Atomic Weights of the International Union of Pure and Applied Chemistry.

The acceptance of the name was premature because both Russian and American efforts now completely rule out the possibility of any isotope of Element 102 having a half-life of 10 min in the vicinity of 8.5 MeV. Early work in 1957 on the search for this element, in Russia at the Kurchatov Institute, was marred by the assignment of 8.9 +/- 0.4 MeV alpha radiation with a half-life of 2 to 40 sec, which was too indefinite to support discovery claims.

Confirmatory experiments at Berkeley in 1966 have shown the existence of 254102 with a 55-s half-life, 252102 with a 2.3-s half-life, and 257102 with a 23-s half-life.

Following tradition giving the right to name an element to the discoverer(s), the Berkeley group in 1967, suggested that the hastily given name nobelium along with the symbol No , be retained.

Images

Propriétés

Propriétés chimiques

Électronégativité (Pauling)
1,3 Comparer : Électronégativité (Pauling) de tous les éléments →
Affinité électronique
-2,36 eV (valeur négative — l'atome ne devrait pas lier d'électron supplémentaire)
Énergie d’ionisation (1re)
6,62621 eV Comparer : Énergie d’ionisation (1re) de tous les éléments →
Énergie d’ionisation (2e)
12,930045 eV Comparer : Énergie d’ionisation (2e) de tous les éléments →
Énergie d’ionisation (3e)
25,800089 eV Comparer : Énergie d’ionisation (3e) de tous les éléments →
Énergie d’ionisation (4e)
41,500143 eV Comparer : Énergie d’ionisation (4e) de tous les éléments →
Énergie d’ionisation (5e)
60,000207 eV Comparer : Énergie d’ionisation (5e) de tous les éléments →
États d’oxydation
+2, +3 Comparer : États d’oxydation de tous les éléments →
Électrons de valence
3 Comparer : Électrons de valence de tous les éléments →
Configuration électronique
[Rn] 7s2 5f14

Propriétés thermodynamiques

Enthalpie de sublimation
4,042079 eV
Enthalpie d’atomisation
4,042079 eV

Propriétés nucléaires

Protons
102 Comparer : Protons de tous les éléments →
Neutrons
159 Comparer : Neutrons de tous les éléments →
Isotopes connus
17 Comparer : Isotopes connus de tous les éléments →
Isotopes stables
0 Comparer : Isotopes stables de tous les éléments →
Nombre de masse (isotope le plus stable)
259
Isotope le plus stable
No-261
Année de découverte
1957

Abondance

N/D

Structure cristalline

N/D

Structure électronique

Électrons par couche
2, 8, 18, 32, 32, 8, 2 Comparer : Électrons par couche de tous les éléments →

Identifiants

Numéro CAS
10028-14-5 Comparer : Numéro CAS de tous les éléments →
Symbole de terme
1S0
InChI
InChI=1S/No
Clé InChI
ORQBXQOJMQIAOY-UHFFFAOYSA-N

Configuration électronique Mesuré

Charge ionique
Protons 102
Électrons 102
Charge Neutre
Configuration No: 5f¹⁴ 7s²
Configuration électronique
Mesuré
[Rn] 5f¹⁴ 7s²
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 5f¹⁴ 7s²
Diagramme d’orbitales
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
10/10
6p
6/6
7s
2/2
5f
14/14
Nombre total d’électrons: 102 Non appariés: 0

Modèle atomique

Protons 102
Neutrons 152
Électrons 102
Nombre de masse 254
Stabilité Radioactif

Les isotopes diffèrent par leur nombre de neutrons, leur masse et leur stabilité — pas par la configuration électronique de l’atome neutre.

Modèle atomique schématique, non à l’échelle.

Empreinte atomique

Spectre d’émission / d’absorption

0 / 0 (0 0 avec intensité)
Mesuré
Émission Visible : 380–750 nm

Distribution isotopique

Aucun isotope stable.

Nombre de masseMasse atomique (u)Abondance naturelleDemi-vie
251 Radioactif251,08894 ± 0,00012N/D800 ms
260 Radioactif260,10264 ± 0,00022N/D106 ms
259 Radioactif259,10103 ± 0,00011N/D58 minutes
249 Radioactif249,0878 ± 0,0003N/D57 us
254 Radioactif254,090956 ± 0,000011N/D51.2 secondes
Mesuré

Phase / État

1 atm / 101,325 kPa
Solide 25 °C (298,15 K)

Explication: 801,9 °C en dessous du point de sublimation (826,85 °C)

Point de sublimation 826,85 °C
0 K Température actuelle: 25 °C 6000 K
Échelle des phases

Schématique, non à l’échelle

Solide
Gaz
Sublimation
25°C
Solide
Liquide
Gaz
Actuel

Points de transition de phase

Point de sublimation Littérature scientifique
826,85 °C
Phase actuelle Calculé
Solide

Énergies de transition

Enthalpie de sublimation Littérature scientifique
4,042079 eV

Énergie nécessaire pour sublimer 1 mol au point de sublimation

Masse volumique

Masse volumique de référence Littérature scientifique
9900 kg/m³

Dans les conditions standard

Masse volumique actuelle Calculé
9900 kg/m³

Dans les conditions standard

Spectres atomiques

Affichage de 10 sur 102. Tri par charge ionique croissante.

Niveaux répertoriés ?

IonChargeNiveaux
No I 02
No II +12
No III +22
No IV +32
No V +42
No VI +52
No VII +62
No VIII +72
No IX +82
No X +92
Niveaux répertoriés par le NIST →
102 No 259

Nobelium — Visualiseur d’orbitales atomiques

[Rn]7s25f14
Niveaux d’énergie 2 8 18 32 32 8 2
États d’oxydation +2, +3
HOMO 7s n=7 · l=0 · m=0
Nobelium — Aperçu du visualiseur d’orbitales atomiques
Three.js se charge uniquement à la demande
102 No 259

Nobelium — Visualiseur de structure cristalline

Données de structure cristalline indisponibles

Rayons ioniques

ChargeCoordinenceSpinRayon
+26N/D110.00000000000001 pm
+39N/D108.5 pm

Composés

No
259,101 u

Isotopes (5)

Ten isotopes are now recognized, one of which 255102 has a half-life of 3 minutes.

Nombre de masseMasse atomique (u)Abondance naturelleDemi-vieMode de désintégration
251 Radioactif251,08894 ± 0,00012N/D800 ms
α =83±1.6%β+ ?SF<0.3%
260 Radioactif260,10264 ± 0,00022N/D106 ms
SF =100%
259 Radioactif259,10103 ± 0,00011N/D58 minutes
α =75±0.4%ε =25±0.4%SF<10%
249 Radioactif249,0878 ± 0,0003N/D57 us
β+ ?α ?
254 Radioactif254,090956 ± 0,000011N/D51.2 secondes
α =90±0.1%β+ =10±0.1%SF =0.17±0.2%
251 Radioactif
Masse atomique (u) 251,08894 ± 0,00012
Abondance naturelle N/D
Demi-vie 800 ms
Mode de désintégration
α =83±1.6%β+ ? +1
260 Radioactif
Masse atomique (u) 260,10264 ± 0,00022
Abondance naturelle N/D
Demi-vie 106 ms
Mode de désintégration
SF =100%
259 Radioactif
Masse atomique (u) 259,10103 ± 0,00011
Abondance naturelle N/D
Demi-vie 58 minutes
Mode de désintégration
α =75±0.4%ε =25±0.4% +1
249 Radioactif
Masse atomique (u) 249,0878 ± 0,0003
Abondance naturelle N/D
Demi-vie 57 us
Mode de désintégration
β+ ?α ?
254 Radioactif
Masse atomique (u) 254,090956 ± 0,000011
Abondance naturelle N/D
Demi-vie 51.2 secondes
Mode de désintégration
α =90±0.1%β+ =10±0.1% +1

Propriétés étendues

Rayons covalents (données étendues)

Rayon covalent (Pyykkö)
176 pm

Rayons de van der Waals

UFF
324,8 pm

Échelles de numérotation

Mendeleev
40
Pettifor
35
Glawe
46

Échelles d’électronégativité

Ghosh
0

Polarisabilité et dispersion

Polarisabilité dipolaire
110 a.u.
Polarisabilité dipolaire (incertitude)
6 a.u.

Transitions de phase et allotropes

Point de fusion1100,15 K

Catégories d’états d’oxydation

+2 extended
+3 main

Données de référence avancées

Détail des rayons cristallins (2)
ChargeCNSpinrcrystal (pm)Origine
2VI124estimated,
3IX—122,5
Modes de désintégration des isotopes (39)
IsotopeModeIntensité
248SF—
249B+—
249A—
250SF100%
250A—
250B+—
251A83%
251B+—
251SF0,3%
252A67,6%

Données complémentaires

Références

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
No

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Nobelium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

Note sur la licence: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Nobelium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

Note sur la licence: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Nobelium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Nobelium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Nobelium

This section provides all form of data related to element Nobelium.

9 PubChem Elements
Nobelium

The element property data was retrieved from publications.

Dernière mise à jour:

Données vérifiées:

Le contenu est vérifié au regard des dernières données scientifiques.