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Fr 87

Francium (Fr)

alkali-metal
Periode: 7 Gruppe: 1 Block: s

Solid

Standardatomgewicht

[223]

Elektronenkonfiguration

[Rn] 7s1

Schmelzpunkt

26,85 °C

Siedepunkt

N/A

Dichte

1870 kg/m³

Oxidationszustände

+1

Elektronegativität (Pauling)

0,7

Ionisierungsenergie (1.)

4,072741 eV

Entdeckungsjahr

1939

Atomradius

N/A

Details

Namensherkunft Named for France, the nation of its discovery.
Entdeckungsland France
Entdecker Marguerite Derey

Francium is the heaviest known alkali metal and a member of group 1. All of its isotopes are radioactive, and the element occurs naturally only as fleeting decay products in uranium and thorium series minerals. Its chemistry is expected and partly observed to resemble an extremely electropositive form of caesium, dominated by the +1 oxidation state. Because the longest-lived isotope, ²²³Fr, has a half-life of only about 22 minutes, francium has no bulk technological role.

Francium was discovered in 1939 by Marguerite Perey, a physicist at the Curie Institute in Paris, France (Fig. IUPAC.87.1). 223Fr (with a half-life of 22 min) occurs naturally in uranium minerals as a result of actinium decay. However, it is estimated that no more than approximately 30 g of francium is present in the Earth’s crust at any time. Francium can be produced artificially for research by bombarding thorium with protons. Francium was named in honor of Perey’s home country, France [575], [576], [577]. Francium has no known isotopic applications outside of scientific research.

Francium was discovered by Marguerite Catherine Perey, a French chemist, in 1939 while analyzing actinium's decay sequence. Although considered a natural element, scientists estimate that there is no more than one ounce of francium in the earth's crust at one time. Since there is so little naturally occurring francium on earth, scientists must produce francium in order to study it. Francium can be produced by bombarding thorium with protons or by bombarding radium with neutrons. Francium's most stable isotope, francium-223, has a half-life of about 22 minutes. It decays into radium-223 through beta decay or into astatine-219 through alpha decay.

Discovered in 1939 by Mlle. Marguerite Perey of the Curie Institute, Paris. Francium, the heaviest known member of the alkali metals series, occurs as a result of an alpha disintegration of actinium. It can also be made artificially by bombarding thorium with protons. While it occurs naturally in uranium minerals, there is probably less than an ounce of francium at any time in the total crust of the earth. It has the highest equivalent weight of any element, and is the most unstable of the first 101 elements of the periodic system. Thirty-three isotopes of francium are recognized. The longest lived 223Fr (Ac, K), a daughter of 227Ac, has a half-life of 22 min. This is the only isotope of francium occurring in nature. Because all known isotopes of francium are highly unstable, knowledge of the chemical properties of this element comes from radiochemical techniques. No weighable quantity of the element has been prepared or isolated. The chemical properties of francium most resemble cesium.

Bilder

Eigenschaften

Chemisch

Elektronegativität (Pauling)
0,7 Vergleiche Elektronegativität (Pauling) aller Elemente →
Elektronegativität (Allen)
0,67
Elektronenaffinität
0,491 eV
Ionisierungsenergie (1.)
4,072741 eV Vergleiche Ionisierungsenergie (1.) aller Elemente →
Ionisierungsenergie (2.)
22,400077 eV Vergleiche Ionisierungsenergie (2.) aller Elemente →
Ionisierungsenergie (3.)
33,500115 eV Vergleiche Ionisierungsenergie (3.) aller Elemente →
Ionisierungsenergie (4.)
39,100135 eV Vergleiche Ionisierungsenergie (4.) aller Elemente →
Ionisierungsenergie (5.)
50,000172 eV Vergleiche Ionisierungsenergie (5.) aller Elemente →
Oxidationszustände
+1 Vergleiche Oxidationszustände aller Elemente →
Valenzelektronen
1 Vergleiche Valenzelektronen aller Elemente →
Elektronenkonfiguration
[Rn] 7s1

Thermodynamisch

Schmelzwärme
0,02072861 eV Vergleiche Schmelzwärme aller Elemente →
Verdampfungswärme
0,67367985 eV Vergleiche Verdampfungswärme aller Elemente →
Sublimationswärme
0,74622998 eV
Atomisierungswärme
0,74622998 eV

Nuklear

Protonen
87 Vergleiche Protonen aller Elemente →
Neutronen
136 Vergleiche Neutronen aller Elemente →
Bekannte Isotope
37 Vergleiche Bekannte Isotope aller Elemente →
Stabile Isotope
0 Vergleiche Stabile Isotope aller Elemente →
Massenzahl (stabilstes)
223
Stabilstes Isotop
Fr-223
Entdeckungsjahr
1939

Häufigkeit

N/A

Kristallstruktur

N/A

Elektronische Struktur

Elektronen pro Schale
2, 8, 18, 32, 18, 8, 1 Vergleiche Elektronen pro Schale aller Elemente →

Identifikatoren

CAS-Nummer
7440-73-5 Vergleiche CAS-Nummer aller Elemente →
Termsymbol
2S1/2
InChI
InChI=1S/Fr
InChI-Key
KLMCZVJOEAUDNE-UHFFFAOYSA-N

Elektronenkonfiguration Gemessen

Ionenladung
Protonen 87
Elektronen 87
Ladung Neutral
Konfiguration Fr: 7s¹
Elektronenkonfiguration
Gemessen
[Rn] 7s¹
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s² 6p⁶ 7s¹
Orbitaldiagramm
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
2/2
4f
14/14
5d
10/10
6p
6/6
7s
1/2 1↑
Gesamtelektronen: 87 Ungepaart: 1 ?

Atommodell

Protonen 87
Neutronen 128
Elektronen 87
Massenzahl 215
Stabilität Radioaktiv

Isotope ändern die Neutronenzahl, Masse und Stabilität — nicht die Elektronenkonfiguration eines neutralen Atoms.

Schematisches Atommodell, nicht maßstabsgetreu.

Atomarer Fingerabdruck

Emissions- / Absorptionsspektrum

25 / 94 (0 0 mit Intensität)
Gemessen
Emission Sichtbar: 380–750 nm

Isotopenverteilung

Keine stabilen Isotope.

MassenzahlAtommasse (u)Natürliche HäufigkeitHalbwertszeit
233 Radioaktiv233,05264 ± 0,00032N/A900 ms
216 Radioaktiv216,0031899 ± 0,0000045N/A700 ns
203 Radioaktiv203,0009407 ± 0,0000067N/A550 ms
202 Radioaktiv202,00332 ± 0,000055N/A372 ms
215 Radioaktiv215,0003418 ± 0,0000076N/A90 ns
Gemessen

Phase / Zustand

1 atm / 101.325 kPa
Fest 25 °C (298,15 K)

Grund: 1,9 °C unter Schmelzpunkt (26,85 °C)

Schmelzpunkt 26,85 °C
0 K Aktuelle Temperatur: 25 °C 6000 K
Phasenzeitlinie

Schematisch, nicht maßstabsgetreu

Fest
Flüssig + Gas
Schmelzen
25°C
Fest
Flüssig
Gas
Aktuell

Phasenübergangspunkte

Schmelzpunkt Literatur
26,85 °C
Aktuelle Phase Berechnet
Fest

Übergangsenergien

Schmelzwärme Literatur
0,02072861 eV

Energie benötigt, um 1 mol am Schmelzpunkt zu schmelzen

Verdampfungswärme Literatur
0,67367985 eV

Energie benötigt, um 1 mol am Siedepunkt zu verdampfen

Sublimationswärme Literatur
0,74622998 eV

Energie benötigt, um 1 mol am Sublimationspunkt zu sublimieren

Dichte

Referenzdichte Literatur
1870 kg/m³

Bei Standardbedingungen

Aktuelle Dichte Berechnet
1870 kg/m³

Bei Standardbedingungen

Atomspektren

10 von 87 angezeigt. Sortiert nach Ionenladung (aufsteigend).

Liniendaten ?

IonLadungGesamtlinienÜbergangswahrscheinlichkeitenNiveau-Bezeichnungen
Fr I 0149149149
NIST Liniendaten →

Niveaudaten ?

IonLadungNiveaus
Fr I 0123
Fr II +12
Fr III +22
Fr IV +32
Fr V +42
Fr VI +52
Fr VII +62
Fr VIII +72
Fr IX +82
Fr X +92
NIST Niveaudaten →
87 Fr 223

Francium — Atomorbital-Visualisierer

[Rn]7s1
Energieniveaus 2 8 18 32 18 8 1
Oxidationszustände +1
HOMO 7s n=7 · l=0 · m=0
Francium — Atomorbital-Visualisierer Vorschau
Three.js lädt nur auf Anfrage
87 Fr 223

Francium — Kristallstruktur-Visualisierer

Kristallstrukturdaten nicht verfügbar

Kristallstruktur: bcc

Ionenradien

LadungKoordinationSpinRadius
+16N/A180 pm

Verbindungen

Fr
223,020 u
Fr
221,014 u
Fr
223,020 u
Fr
222,018 u
Fr
220,012 u

Isotope (5)

MassenzahlAtommasse (u)Natürliche HäufigkeitHalbwertszeitZerfallsart
233 Radioaktiv233,05264 ± 0,00032N/A900 ms
β- =100%β-n ?
216 Radioaktiv216,0031899 ± 0,0000045N/A700 ns
α =100%β+ ?
203 Radioaktiv203,0009407 ± 0,0000067N/A550 ms
α ≈100%β+ ?
202 Radioaktiv202,00332 ± 0,000055N/A372 ms
α ≈100%β+ ?
215 Radioaktiv215,0003418 ± 0,0000076N/A90 ns
α =100%
233 Radioaktiv
Atommasse (u) 233,05264 ± 0,00032
Natürliche Häufigkeit N/A
Halbwertszeit 900 ms
Zerfallsart
β- =100%β-n ?
216 Radioaktiv
Atommasse (u) 216,0031899 ± 0,0000045
Natürliche Häufigkeit N/A
Halbwertszeit 700 ns
Zerfallsart
α =100%β+ ?
203 Radioaktiv
Atommasse (u) 203,0009407 ± 0,0000067
Natürliche Häufigkeit N/A
Halbwertszeit 550 ms
Zerfallsart
α ≈100%β+ ?
202 Radioaktiv
Atommasse (u) 202,00332 ± 0,000055
Natürliche Häufigkeit N/A
Halbwertszeit 372 ms
Zerfallsart
α ≈100%β+ ?
215 Radioaktiv
Atommasse (u) 215,0003418 ± 0,0000076
Natürliche Häufigkeit N/A
Halbwertszeit 90 ns
Zerfallsart
α =100%

Spektrallinien

Wellenlänge (nm)IntensitätIonenstufeTypÜbergangGenauigkeitQuelle
422.56552 nmN/AFr Iemission7s 2S → 8p 2P*GemessenNIST
432.53607 nmN/AFr Iemission7s 2S → 8p 2P*GemessenNIST
494.61573 nmN/AFr Iemission7p 2P* → 20d 2DGemessenNIST
495.91444 nmN/AFr Iemission7p 2P* → 19d 2DGemessenNIST
496.90308 nmN/AFr Iemission7p 2P* → 20s 2SGemessenNIST
497.49878 nmN/AFr Iemission7p 2P* → 18d 2DGemessenNIST
498.7192 nmN/AFr Iemission7p 2P* → 19s 2SGemessenNIST
499.45999 nmN/AFr Iemission7p 2P* → 17d 2DGemessenNIST
500.99176 nmN/AFr Iemission7p 2P* → 18s 2SGemessenNIST
501.92929 nmN/AFr Iemission7p 2P* → 16d 2DGemessenNIST
503.88964 nmN/AFr Iemission7p 2P* → 17s 2SGemessenNIST
505.10105 nmN/AFr Iemission7p 2P* → 15d 2DGemessenNIST
507.66912 nmN/AFr Iemission7p 2P* → 16s 2SGemessenNIST
509.27532 nmN/AFr Iemission7p 2P* → 14d 2DGemessenNIST
512.73622 nmN/AFr Iemission7p 2P* → 15s 2SGemessenNIST
514.93307 nmN/AFr Iemission7p 2P* → 13d 2DGemessenNIST
519.7664 nmN/AFr Iemission7p 2P* → 14s 2SGemessenNIST
522.89168 nmN/AFr Iemission7p 2P* → 12d 2DGemessenNIST
529.95916 nmN/AFr Iemission7p 2P* → 13s 2SGemessenNIST
534.64166 nmN/AFr Iemission7p 2P* → 11d 2DGemessenNIST
539.61762 nmN/AFr Iemission7p 2P* → 20d 2DGemessenNIST
539.6469 nmN/AFr Iemission7p 2P* → 20d 2DGemessenNIST
541.15779 nmN/AFr Iemission7p 2P* → 19d 2DGemessenNIST
541.19321 nmN/AFr Iemission7p 2P* → 19d 2DGemessenNIST
542.37083 nmN/AFr Iemission7p 2P* → 20s 2SGemessenNIST
543.03716 nmN/AFr Iemission7p 2P* → 18d 2DGemessenNIST
543.08061 nmN/AFr Iemission7p 2P* → 18d 2DGemessenNIST
544.53524 nmN/AFr Iemission7p 2P* → 19s 2SGemessenNIST
545.36417 nmN/AFr Iemission7p 2P* → 17d 2DGemessenNIST
545.4185 nmN/AFr Iemission7p 2P* → 17d 2DGemessenNIST
545.63748 nmN/AFr Iemission7p 2P* → 12s 2SGemessenNIST
547.24565 nmN/AFr Iemission7p 2P* → 18s 2SGemessenNIST
548.29545 nmN/AFr Iemission7p 2P* → 16d 2DGemessenNIST
548.36447 nmN/AFr Iemission7p 2P* → 16d 2DGemessenNIST
550.70515 nmN/AFr Iemission7p 2P* → 17s 2SGemessenNIST
552.06365 nmN/AFr Iemission7p 2P* → 15d 2DGemessenNIST
552.15244 nmN/AFr Iemission7p 2P* → 15d 2DGemessenNIST
553.17161 nmN/AFr Iemission7p 2P* → 10d 2DGemessenNIST
555.22268 nmN/AFr Iemission7p 2P* → 16s 2SGemessenNIST
557.02549 nmN/AFr Iemission7p 2P* → 14d 2DGemessenNIST
557.14445 nmN/AFr Iemission7p 2P* → 14d 2DGemessenNIST
561.28917 nmN/AFr Iemission7p 2P* → 15s 2SGemessenNIST
563.7589 nmN/AFr Iemission7p 2P* → 13d 2DGemessenNIST
563.92284 nmN/AFr Iemission7p 2P* → 13d 2DGemessenNIST
569.72475 nmN/AFr Iemission7p 2P* → 14s 2SGemessenNIST
571.87464 nmN/AFr Iemission7p 2P* → 11s 2SGemessenNIST
573.24676 nmN/AFr Iemission7p 2P* → 12d 2DGemessenNIST
573.48185 nmN/AFr Iemission7p 2P* → 12d 2DGemessenNIST
585.3491 nmN/AFr Iemission7p 2P* → 9d 2DGemessenNIST
587.29 nmN/AFr Iemission7p 2P* → 11d 2DGemessenNIST
587.64619 nmN/AFr Iemission7p 2P* → 11d 2DGemessenNIST
600.95745 nmN/AFr Iemission7p 2P* → 12s 2SGemessenNIST
609.52762 nmN/AFr Iemission7p 2P* → 10d 2DGemessenNIST
610.10952 nmN/AFr Iemission7p 2P* → 10d 2DGemessenNIST
618.5596 nmN/AFr Iemission6d 2D → 20p 2P*GemessenNIST
618.7831 nmN/AFr Iemission6d 2D → 20p 2P*GemessenNIST
621.0658 nmN/AFr Iemission6d 2D → 19p 2P*GemessenNIST
621.3414 nmN/AFr Iemission6d 2D → 19p 2P*GemessenNIST
621.98126 nmN/AFr Iemission7p 2P* → 10s 2SGemessenNIST
624.178 nmN/AFr Iemission6d 2D → 18p 2P*GemessenNIST
624.5235 nmN/AFr Iemission6d 2D → 18p 2P*GemessenNIST
626.3009 nmN/AFr Iemission6d 2D → 20p 2P*GemessenNIST
628.1118 nmN/AFr Iemission6d 2D → 17p 2P*GemessenNIST
628.5529 nmN/AFr Iemission6d 2D → 17p 2P*GemessenNIST
628.8704 nmN/AFr Iemission6d 2D → 19p 2P*GemessenNIST
632.0616 nmN/AFr Iemission6d 2D → 18p 2P*GemessenNIST
632.9403 nmN/AFr Iemission7p 2P* → 11s 2SGemessenNIST
633.1901 nmN/AFr Iemission6d 2D → 16p 2P*GemessenNIST
633.7661 nmN/AFr Iemission6d 2D → 16p 2P*GemessenNIST
636.0957 nmN/AFr Iemission6d 2D → 17p 2P*GemessenNIST
639.9141 nmN/AFr Iemission6d 2D → 15p 2P*GemessenNIST
640.6887 nmN/AFr Iemission6d 2D → 15p 2P*GemessenNIST
641.3044 nmN/AFr Iemission6d 2D → 16p 2P*GemessenNIST
648.2027 nmN/AFr Iemission6d 2D → 15p 2P*GemessenNIST
648.421 nmN/AFr Iemission7p 2P* → 9d 2DGemessenNIST
649.103 nmN/AFr Iemission6d 2D → 14p 2P*GemessenNIST
649.4876 nmN/AFr Iemission7p 2P* → 9d 2DGemessenNIST
650.1812 nmN/AFr Iemission6d 2D → 14p 2P*GemessenNIST
650.7242 nmN/AFr Iemission7p 2P* → 8d 2DGemessenNIST
657.633 nmN/AFr Iemission6d 2D → 14p 2P*GemessenNIST
662.174 nmN/AFr Iemission6d 2D → 13p 2P*GemessenNIST
663.746 nmN/AFr Iemission6d 2D → 13p 2P*GemessenNIST
671.054 nmN/AFr Iemission6d 2D → 13p 2P*GemessenNIST
681.787 nmN/AFr Iemission6d 2D → 12p 2P*GemessenNIST
684.222 nmN/AFr Iemission6d 2D → 12p 2P*GemessenNIST
691.204 nmN/AFr Iemission6d 2D → 12p 2P*GemessenNIST
694.8987 nmN/AFr Iemission7p 2P* → 10s 2SGemessenNIST
713.491 nmN/AFr Iemission6d 2D → 11p 2P*GemessenNIST
717.615 nmN/AFr Iemission6d 2D → 11p 2P*GemessenNIST
717.98664 nmN/AFr Iemission7s 2S → 7p 2P*GemessenNIST
723.811 nmN/AFr Iemission6d 2D → 11p 2P*GemessenNIST
728.5892 nmN/AFr Iemission7p 2P* → 8d 2DGemessenNIST
730.9713 nmN/AFr Iemission7p 2P* → 8d 2DGemessenNIST
744.1976 nmN/AFr Iemission7p 2P* → 9s 2SGemessenNIST

Erweiterte Eigenschaften

Kovalente Radien (Erweitert)

Kovalenzradius (Pyykkö)
223 pm
Kovalenzradius (Pyykkö, doppelt)
218 pm

Van-der-Waals-Radien

Truhlar
348 pm
UFF
490 pm
MM3
364 pm

Atom- & Metallische Radien

Atomradius (Rahm)
258 pm

Nummerierungsskalen

Mendeleev
6
Pettifor
7
Glawe
7

Elektronegativitätsskalen

Ghosh
0

Polarisierbarkeit & Dispersion

Dipolpolarisierbarkeit
317,8 a.u.
Dipolpolarisierbarkeit (Uns.)
2,4 a.u.

Phasenübergänge & Allotrope

Schmelzpunkt294,15 K

Oxidationszustands-Kategorien

+1 main

Erweiterte Referenzdaten

Kristallradien-Details (1)
LadungCNSpinrcrystal (pm)Herkunft
1VI194Ahrens (1952) ionic radius,
Isotopenzerfallsarten (60)
IsotopModusIntensität
197A100%
198A100%
199A100%
199B+—
200A100%
200B+—
200B+SF—
201A100%
201B+—
202A100%
Röntgenstreufaktoren (516)
Energie (eV)f₁f₂
10—0,05044
10,1617—0,06059
10,3261—0,07277
10,4931—0,08938
10,6628—0,11712
10,8353—0,15347
11,0106—0,20109
11,1886—0,26349
11,3696—0,40321
11,5535—0,63759

Zusätzliche Daten

Referenzen

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Fr

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Francium

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

Lizenzhinweis: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Francium

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

Lizenzhinweis: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Francium

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Francium

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Francium

This section provides all form of data related to element Francium.

9 PubChem Elements
Francium

The element property data was retrieved from publications.

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Daten verifiziert:

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