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Au 79

Gold (Au)

transition-metal
Periode: 6 Gruppe: 11 Block: d

Solid

Standardatomgewicht

196,966569 u

Elektronenkonfiguration

[Xe] 6s1 4f14 5d10

Schmelzpunkt

1064,18 °C

Siedepunkt

2855,85 °C

Dichte

1,9282e+4 kg/m³

Oxidationszustände

−3, −2, −1, 0, +1, +2, +3, +5

Elektronegativität (Pauling)

2,54

Ionisierungsenergie (1.)

9,225554 eV

Entdeckungsjahr

N/A

Atomradius

135 pm

Details

Namensherkunft Anglo-Saxon: geolo (yellow); symbol from Latin: aurum (shining dawn).
Entdecker Known to the ancients.

Gold is a dense, soft transition metal with exceptional resistance to oxidation and corrosion. It is usually found native or alloyed with silver and other precious metals, rather than as common simple ores. Its chemistry is dominated by relativistic effects, which help give the metal its yellow color and influence stable oxidation states. Gold combines high electrical conductivity, malleability, chemical nobility, and cultural value in a way unmatched by most elements.

It is estimated that all the gold in the world, so far refined, could be placed in a single cube 60 ft. on a side. Of all the elements, gold in its pure state is undoubtedly the most beautiful. It is metallic, having a yellow color when in a mass, but when finely divided it may be black, ruby, or purple. The Purple of Cassius is a delicate test for auric gold. It is the most malleable and ductile metal; 1 oz. of gold can be beaten out to 300 ft2. It is a soft metal and is usually alloyed to give it more strength. It is a good conductor of heat and electricity, and is unaffected by air and most reagents.

The name derives from the Sanskrit jval for "shine", the Teutonic word gulth for "shining metal", and the Anglo-Saxon gold of unknown origin. The symbol Au derives from the Latin aurum, for Aurora, the goddess of dawn. Gold was known and highly valued in prehistoric times.

An attractive and highly valued metal, gold has been known for at least 5500 years. Gold is sometimes found free in nature but it is usually found in conjunction with silver, quartz (SiO2), calcite (CaCO3), lead, tellurium, zinc or copper. There is roughly 1 milligram of gold dissolved in every ton of seawater, although extracting it currently costs more than the gold is worth. It has been estimated that all of the gold that has currently been refined could be placed in a cube measuring 20 meters on a side.

Known and highly valued from earliest times, gold is found in nature as the free metal and in tellurides; it is very widely distributed and is almost always associated with quartz or pyrite.

Bilder

Eigenschaften

Physikalisch

Atomradius (empirisch)
135 pm Vergleiche Atomradius (empirisch) aller Elemente →
Kovalenzradius
136 pm Vergleiche Kovalenzradius aller Elemente →
Van-der-Waals-Radius
166 pm Vergleiche Van-der-Waals-Radius aller Elemente →
Metallradius
134 pm Vergleiche Metallradius aller Elemente →
Dichte
1,9282 × 104 kg/m³ Vergleiche Dichte aller Elemente →
Molares Volumen
0,0102 L/mol
Aggregatzustand bei Standardbedingungen
Fest Vergleiche Aggregatzustand bei Standardbedingungen aller Elemente →
Schmelzpunkt
1064,18 °C Vergleiche Schmelzpunkt aller Elemente →
Siedepunkt
2855,85 °C Vergleiche Siedepunkt aller Elemente →
Wärmeleitfähigkeit
318 W/(m·K) Vergleiche Wärmeleitfähigkeit aller Elemente →
Spezifische Wärmekapazität
0,129 J/(g·K) Vergleiche Spezifische Wärmekapazität aller Elemente →
Molare Wärmekapazität
25,418 J/(mol·K) Vergleiche Molare Wärmekapazität aller Elemente →
Kristallstruktur
Flächenzentriert kubisch Vergleiche Kristallstruktur aller Elemente →

Chemisch

Elektronegativität (Pauling)
2,54 Vergleiche Elektronegativität (Pauling) aller Elemente →
Elektronegativität (Allen)
1,92
Elektronenaffinität
2,3086 eV
Ionisierungsenergie (1.)
9,225554 eV Vergleiche Ionisierungsenergie (1.) aller Elemente →
Ionisierungsenergie (2.)
20,20307 eV Vergleiche Ionisierungsenergie (2.) aller Elemente →
Ionisierungsenergie (3.)
30,000103 eV Vergleiche Ionisierungsenergie (3.) aller Elemente →
Ionisierungsenergie (4.)
45,000155 eV Vergleiche Ionisierungsenergie (4.) aller Elemente →
Ionisierungsenergie (5.)
60,000207 eV Vergleiche Ionisierungsenergie (5.) aller Elemente →
Oxidationszustände
−3, −2, −1, 0, +1, +2, +3, +5 Vergleiche Oxidationszustände aller Elemente →
Valenzelektronen
11 Vergleiche Valenzelektronen aller Elemente →
Elektronenkonfiguration
[Xe] 6s1 4f14 5d10

Thermodynamisch

Schmelzwärme
0,13007203 eV Vergleiche Schmelzwärme aller Elemente →
Verdampfungswärme
3,358035 eV Vergleiche Verdampfungswärme aller Elemente →
Sublimationswärme
3,814064 eV
Atomisierungswärme
3,814064 eV
Atomisierungsenthalpie
3,816137 eV

Häufigkeit

Häufigkeit (Erdkruste)
0,004 mg/kg Vergleiche Häufigkeit (Erdkruste) aller Elemente →
Häufigkeit (Ozean)
4 × 10−6 mg/L Vergleiche Häufigkeit (Ozean) aller Elemente →

Kristallstruktur

Gitterkonstante a
408 pm

Elektronische Struktur

Elektronen pro Schale
2, 8, 18, 32, 18, 1 Vergleiche Elektronen pro Schale aller Elemente →

Identifikatoren

CAS-Nummer
7440-57-5 Vergleiche CAS-Nummer aller Elemente →
Termsymbol
2S1/2
InChI
InChI=1S/Au
InChI-Key
PCHJSUWPFVWCPO-UHFFFAOYSA-N

Elektronenkonfiguration Gemessen

Ionenladung
Protonen 79
Elektronen 79
Ladung Neutral
Konfiguration Au: 4f¹⁴ 5d¹⁰ 6s¹
Elektronenkonfiguration
Gemessen
[Xe] 4f¹⁴ 5d¹⁰ 6s¹
1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² 4p⁶ 4d¹⁰ 5s² 5p⁶ 4f¹⁴ 5d¹⁰ 6s¹
Orbitaldiagramm
1s
2/2
2s
2/2
2p
6/6
3s
2/2
3p
6/6
4s
2/2
3d
10/10
4p
6/6
5s
2/2
4d
10/10
5p
6/6
6s
1/2 1↑
4f
14/14
5d
10/10
Gesamtelektronen: 79 Ungepaart: 1 ?

Atommodell

Protonen 79
Neutronen 118
Elektronen 79
Massenzahl 197
Stabilität Stabil

Isotope ändern die Neutronenzahl, Masse und Stabilität — nicht die Elektronenkonfiguration eines neutralen Atoms.

Schematisches Atommodell, nicht maßstabsgetreu.

Atomarer Fingerabdruck

Emissions- / Absorptionsspektrum

0 / 0 (0 0 mit Intensität)
Gemessen
Emission Sichtbar: 380–750 nm

Isotopenverteilung

Monoisotopisches Element
Einziges natürlich vorkommendes Isotop: 197 — 100,0000%
197100,0000%MassenzahlNatürliche Häufigkeit (%)
MassenzahlAtommasse (u)Natürliche HäufigkeitHalbwertszeit
197 Stabil196,96656879 ± 0,00000071100,0000%Stabil
Gemessen

Phase / Zustand

1 atm / 101.325 kPa
Fest 25 °C (298,15 K)

Grund: 1039,2 °C unter Schmelzpunkt (1064,18 °C)

Schmelzpunkt 1064,18 °C
Siedepunkt 2855,85 °C
Unter Schmelzpunkt um 1039,2 °C
0 K Aktuelle Temperatur: 25 °C 6000 K
Phasenzeitlinie

Schematisch, nicht maßstabsgetreu

Fest
Flüssig
Gas
Schmelzen
Sieden
25°C
Fest
Flüssig
Gas
Aktuell

Phasenübergangspunkte

Schmelzpunkt Literatur
1064,18 °C
Siedepunkt Literatur
2855,85 °C
Aktuelle Phase Berechnet
Fest

Übergangsenergien

Schmelzwärme Literatur
0,13007203 eV

Energie benötigt, um 1 mol am Schmelzpunkt zu schmelzen

Verdampfungswärme Literatur
3,358035 eV

Energie benötigt, um 1 mol am Siedepunkt zu verdampfen

Sublimationswärme Literatur
3,814064 eV

Energie benötigt, um 1 mol am Sublimationspunkt zu sublimieren

Dichte

Referenzdichte Literatur
1,9282e+4 kg/m³

Bei Standardbedingungen

Aktuelle Dichte Berechnet
1,9282e+4 kg/m³

Bei Standardbedingungen

Atomspektren

10 von 79 angezeigt. Sortiert nach Ionenladung (aufsteigend).

Liniendaten ?

IonLadungGesamtlinienÜbergangswahrscheinlichkeitenNiveau-Bezeichnungen
Au I 01912090
Au II +1111010
Au III +215000
NIST Liniendaten →

Niveaudaten ?

IonLadungNiveaus
Au I 075
Au II +148
Au III +22
Au IV +32
Au V +42
Au VI +52
Au VII +62
Au VIII +72
Au IX +82
Au X +92
NIST Niveaudaten →
79 Au 196.966569

Gold — Atomorbital-Visualisierer

[Xe]6s14f145d10
Energieniveaus 2 8 18 32 18 1
Oxidationszustände -3, -2, -1, 0, +1, +2, +3, +5
HOMO 6s n=6 · l=0 · m=0
Gold — Atomorbital-Visualisierer Vorschau
Three.js lädt nur auf Anfrage
79 Au 196.966569

Gold — Kristallstruktur-Visualisierer

Face-Centered Cubic · Pearson cF4
Experimentell
Pearson cF4
Koordinationszahl 12
Packungsdichte 74.000%
Gold — Kristallstruktur-Visualisierer Vorschau
Three.js lädt nur auf Anfrage

Ionenradien

LadungKoordinationSpinRadius
+16N/A137 pm
+34N/A68 pm
+36N/A85 pm
+56N/A56.99999999999999 pm

Verbindungen

Au
196,967 u
Au
197,968 u
Au+3
196,967 u
Au+
196,967 u
Au
198,969 u
Au
194,965 u
Au
200,972 u
Au
196,967 u
Au
192,964 u
Au
193,965 u
Au
199,971 u
Au
195,967 u

Isotope (1)

The most common gold compounds are auric chloride and chlorauric acid, the latter being used in photography for toning the silver image. Gold has 18 isotopes; 198Au, with a half-life of 2.7 days, is used for treating cancer and other diseases. Disodium aurothiomalate is administered intramuscularly as a treatment for arthritis. A mixture of one part nitric acid with three of hydrochloric acid is called aqua regia (because it dissolved gold, the King of Metals). Gold is available commercially with a purity of 99.999+%. For many years the temperature assigned to the freezing point of gold has been 1063.0C; this has served as a calibration point for the International Temperature Scales (ITS-27 and ITS-48) and the International Practical Temperature Scale (IPTS-48). In 1968, a new International Practical Temperature Scale (IPTS-68) was adopted, which demands that the freezing point of gold be changed to 1064.43C. The specific gravity of gold has been found to vary considerably depending on temperature, how the metal is precipitated, and cold-worked.

MassenzahlAtommasse (u)Natürliche HäufigkeitHalbwertszeitZerfallsart
197 Stabil196,96656879 ± 0,00000071100,0000%Stabil
stable
197 Stabil
Atommasse (u) 196,96656879 ± 0,00000071
Natürliche Häufigkeit 100,0000%
Halbwertszeit Stabil
Zerfallsart
stable

Erweiterte Eigenschaften

Kovalente Radien (Erweitert)

Kovalenzradius (Pyykkö)
124 pm
Kovalenzradius (Pyykkö, doppelt)
121 pm
Kovalenzradius (Pyykkö, dreifach)
123 pm

Van-der-Waals-Radien

Batsanov
210 pm
Alvarez
232 pm
UFF
329,3 pm
MM3
243 pm

Atom- & Metallische Radien

Atomradius (Rahm)
226 pm
Metallradius (C12)
144 pm

Nummerierungsskalen

Mendeleev
73
Pettifor
70
Glawe
66

Elektronegativitätsskalen

Ghosh
0
Miedema
5
Gunnarsson–Lundqvist
5
Robles–Bartolotti
4

Polarisierbarkeit & Dispersion

Dipolpolarisierbarkeit
36 a.u.
Dipolpolarisierbarkeit (Uns.)
3 a.u.
C₆ (Gould–Bučko)
427 Ha·Bohr6

Miedema-Parameter

Miedema-Molvolumen
10,2 cm3/mol
Miedema-Elektronendichte
4

Lieferrisiko & Wirtschaftlichkeit

Produktionskonzentration
13
Relatives Lieferrisiko
6
Reservenverteilung
15
Politische Stabilität (Top-Produzent)
24
Politische Stabilität (Top-Reserven)
75

Phasenübergänge & Allotrope

Schmelzpunkt1337,33 K
Siedepunkt3109,15 K

Oxidationszustands-Kategorien

+2 extended
−1 extended
0 extended
−2 extended
+1 extended
−3 extended
+3 main
+5 extended

Erweiterte Referenzdaten

Abschirmkonstanten (14)
nOrbitalσ
1s1,5239
2p4,4868
2s20,6302
3d13,4917
3p22,297
3s23,2372
4d37,472
4f38,3504
4p35,4532
4s34,5868
Kristallradien-Details (4)
LadungCNSpinrcrystal (pm)Herkunft
1VI151Ahrens (1952) ionic radius,
3IVSQ82
3VI99Ahrens (1952) ionic radius,
5VI71
Isotopenzerfallsarten (71)
IsotopModusIntensität
168p—
169p—
169A—
169B+—
170p89%
170A11%
171p100%
171A—
172A100%
172p—
Röntgenstreufaktoren (506)
Energie (eV)f₁f₂
10—1,73645
10,1617—1,81425
10,3261—1,89553
10,4931—1,98045
10,6628—2,06919
10,8353—2,16029
11,0106—2,25522
11,1886—2,35433
11,3696—2,45698
11,5535—2,56237

Zusätzliche Daten

Sources

Sources of this element.

It occurs in veins and alluvial deposits, and is often separated from rocks and other minerals by mining and panning operations. About two thirds of the world's gold output comes from South Africa, and about two thirds of the total U.S. production comes from South Dakota and Nevada. The metal is recovered from its ores by cyaniding, amalgamating, and smelting processes. Refining is also frequently done by electrolysis. Gold occurs in sea water to the extent of 0.1 to 2 mg/ton, depending on the location where the sample is taken. As yet, no method has been found for recovering gold from sea water profitably.

Referenzen (1)

Referenzen

(9)
2 Atomic Mass Data Center (AMDC), International Atomic Energy Agency (IAEA)
Au

The half-life and atomic mass data was provided by the Atomic Mass Data Center at the International Atomic Energy Agency.

3 IUPAC Commission on Isotopic Abundances and Atomic Weights (CIAAW)
Gold

Element data are cited from the Atomic weights of the elements (an IUPAC Technical Report). The IUPAC periodic table of elements can be found at https://iupac.org/what-we-do/periodic-table-of-elements/. Additional information can be found within IUPAC publication doi:10.1515/pac-2015-0703 Copyright © 2020 International Union of Pure and Applied Chemistry.

4 IUPAC Periodic Table of the Elements and Isotopes (IPTEI)

The information are cited from Pure Appl. Chem. 2018; 90(12): 1833-2092, https://doi.org/10.1515/pac-2015-0703.

Lizenzhinweis: Copyright (c) 2020 International Union of Pure and Applied Chemistry. The International Union of Pure and Applied Chemistry (IUPAC) contribution within Pubchem is provided under a CC-BY-NC-ND 4.0 license, unless otherwise stated.
5 Jefferson Lab, U.S. Department of Energy
Gold

Thomas Jefferson National Accelerator Facility (Jefferson Lab) is one of 17 national laboratories funded by the U.S. Department of Energy. The lab's primary mission is to conduct basic research of the atom's nucleus using the lab's unique particle accelerator, known as the Continuous Electron Beam Accelerator Facility (CEBAF). For more information visit https://www.jlab.org/

Lizenzhinweis: Please see citation and linking information: https://education.jlab.org/faq/index.html
6 Los Alamos National Laboratory, U.S. Department of Energy
Gold

The periodic table at the LANL (Los Alamos National Laboratory) contains basic element information together with the history, source, properties, use, handling and more. The provenance data may be found from the link under the source name.

7 NIST Physical Measurement Laboratory
Gold

The periodic table contains NIST's critically-evaluated data on atomic properties of the elements. The provenance data that include data for atomic spectroscopy, X-ray and gamma ray, radiation dosimetry, nuclear physics, and condensed matter physics may be found from the link under the source name. Ref: https://www.nist.gov/pml/atomic-spectra-database

8 PubChem Elements
Gold

This section provides all form of data related to element Gold.

9 PubChem Elements
Gold

The element property data was retrieved from publications.

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Daten verifiziert:

Inhalt wurde gegen aktuelle wissenschaftliche Daten geprüft.